Advance in Inorganic-Organic Nanocomposites-材料合成化学课件PPT.pptVIP

Advance in Inorganic-Organic Nanocomposites Outline With the great progress of our lives and development of technology, human race is demanding longer lives and more advanced medical methods. Nanometer materials is the most promising in the 21st century Organic–inorganic hybrid materials do not represent only a creative alternative to design new materials and compounds for academic research, but their improved or unusual features allow the development of innovative industrial applications. Ⅱ.Preparation methods Sol-gel In situ photopolymerization Intercalation Self-assembly Irradiation 1.Sol-gel preparation Fig10:Phase composition of the samples sintered at different temperatures 600 ?C, 700 ?C, 800 ?C and 900 ?C. Fig11:TEM micrograph of HA nanopowders sintered at 600 ℃. 2.In situ photopolymerization TEM images of as-prepared nanoparticles 3.Intercalation method X-ray powder diffraction Electrical conductivity measurements Conclusions The intercalated polymer chain favors the monolayer arrangement with the thiophene rings lying parallel with the host layers. which should be advantageous for transportation of electrons between the organic and inorganic components. the polymer/MoS2 nanocomposites can be modified, though the different guest–host charge transfers, by incorporating other conducting polymers and their doping, which make them applied in the electronic devices, such as LED, sensors and electrodematerials in Li-batteries. XRD pattern(diffractogram) indicates that a poor crystalline nature of typical apatite crystal structure with broad diffracted peaks could be obtained without any extraneous phases. several peaks of the hydroxyapatite become more distinct and also the widths of the peaks becomemore narrow which suggests an increase in the degree of crystallinity. It can also be seen that additional crystalline phases (-TCP) appear at sintering temperature of 700 ?C and no other crystalline phase can be observed besides hydroxyap