Microbead Patterning on Porous Film with Ordered Arrays of Pores-材料合成化学课件PPT.pptVIP

Microbead Patterning on Porous Film with Ordered Arrays of Pores Outline Some conventional researches A novel method based on evaporative cooling and subsequent water-droplet templating Application Templating methods based on self-assembly techniques Self-assembly of colloidal microspheres on a solid substrate to form a 2D crystalline structure as a template Infusion of other materials in to the voids of the self-assembled microspheres solidification of the material Removal of the template microspheres Problems Difficult to self-assemble template microspheres with long-range order Unstable Easily damaged during the removal the template The Flow Chart of the New Method Optical images of polystyrene/ silica films with ordered arrays of pores: a) low resolution b) high resolution SEM images with different pore sizes How to control pore sizes The amount of TEOS Polystyrene bead sizes The amount of the solution added onto the surface of the substrate How to control pore sizes The relationships between the pore size, polystyrene bead size and amount of TEOS added. Patterning of PS Microbeads on the Porous Films A suspension of polystyrene microbeads was dropped onto the porous film, fully covering the top surface of the film. The film was then shaken on a shaker to allow as many beads to go into the pores as possible. The surface of the film was then washed with water to remove the excess beads. The excess solution was then allowed to evaporate at room temperature. The size influence in patterning the microbeads When the size of the microbeads is bigger than that of the pores, the microbeads sit on the pores rather than entering them When the size of the microbeads is similar to, or a bit smaller than, that of the pores the microbeads can en