结晶学chap3symmgp1.ppt

= ? n ? basic sym derived sym P6mm 6mm Hexagonal P6mm Patterson symmetry P6mm P6mm P ? C F ? I [ det ] ? 2 [ det ] ? 2 PT ? R ( Trigonal ? Rhombohedral Cell ) [ det ] ? 3 R (0, 0, 0) ; (2/3, 1/3, 1/3) ; (1/3, 2/3, 2/3) R (0, 0, 0) ; (1/3, 2/3, 1/3) ; (2/3, 1/3, 2/3) [ det ] ? 3 * Symmetry in two-dimension? 2D unit cell Periodicity in 3-dim. – smallest repeated unit ? unit cell Symmetry in two-dimension Symmetry elements Periodicity in 3-dimetions ---Smallest repeated Unit --- Unit cell Symmetry elements, symbols, matrix representation： Basic symmetry elements ☆ proper rotation Cn → n;