含铜氮化钛抗菌镀膜用于卫浴黄铜的保固性.pdfVIP

含銅氮化鈦抗菌鍍膜用於衛浴黃銅的保固性 防蝕工程　第二十五卷第一期　第47 ~ 54 頁　2011 年3 月 Journal of Chinese Corrosion Engineering, Vol. 25, No. 1, pp. 47 ~ 54 (2011) 1 ,2 3 1 1 陳南宏 、鍾啟仁* 、江忠鍵 、陳克昌 、何主亮 Copper-containing TiN Coatings on Sanitary Ware Copper Alloys for Protection Purpose 1 *,2 3 1 Nan-Hung Chen , Chi-Jen Chung , Chung-Chien Chiang , Keh-Chang Chen , Ju-Liang He1 Received 15 August 2010; received in revised form 1 March 2011; accepted 7 March 2011 目前沐浴器材上常用材料多以黃銅或鋅合金為底材，並施以耐蝕的電鍍鎳/鉻，唯外 觀顏色單調。為求沐浴器材外觀顏色之多樣化及防刮耐磨之強化，本研究擬結合電弧離子 鍍及磁控濺鍍法於同一艙體，以電弧靶座來發射金屬鈦，以濺鍍靶座來發射銅金屬，於預 電鍍鎳/鉻之銅基材表面被覆兼具色彩及抗菌之含銅氮化鈦陶瓷鍍層，進一步對其保固性做 探討。研究結果顯示；相較於預電鍍鎳/鉻之黃銅基材，鍍膜表面硬度、耐磨性和耐蝕性皆 高於預電鍍鎳/鉻之黃銅基材。隨著鍍膜中銅含量由0 at%增加至21.65 at% ，鍍膜表面硬度 及耐磨耗性略為下降，唯腐蝕電位從–371.76 mV 提高到–201.62 mV(vs. Ag/AgCl) ，腐蝕電 流密度則從0.612 µA/cm2 下降至0.489 µA/cm2 。 關鍵詞：電弧離子鍍；磁控濺鍍；含銅氮化鈦；抗菌鍍膜；保固性。 ABSTRACT Copper-zinc alloys, widely used for sanitary ware, were commonly pre-electroplated with corrosion resistant nickel/chromium, resulting in monotonic appearances. An arc ion plating (AIP) technique (for titanium emission) in combination with a magnetron sputtering (MS) source (for copper emission) was employed in a single chamber to develop a color-controllable copper- containing TiN antimicrobial coating in this study. Surface hardness, wear resistance and corrosion resis