gc3n4abo3复合材料的制备及光催化性能研究 word格式.docxVIP

weight ratio of g-C3N4 is 70%, the composite has the best photocatalytic activity, whose rate constant is 228 times and 2.2 times high than that of pure NaTaO3 andg-C3N4. And the PL results show that g-C3N4/NaTaO3 could effectively decrease the recombination rate of photo-induced electrons and holes.To study the mechanism of photocatalysis, we use different scavengers to find the main active species. And the results show super oxygen free radicals (?O2?) plays the main role in the process of photocatalytic activitie, which comes fromphoto-induced electrons. Due to the negative condution band (CB), the electrons in the NaTaO3 have high potential energy. Because there is a small gap between the CB position of g-C3N4 and NaTaO3, it’s not easy for the electron to transfer from g-C3N4 to NaTaO3. And compard with NaTaO3, KTaO3 and NaNbO3 prepared by using the same method have a wide gap of the CB position between them and g-C3N4. Thus the transfer from g-C3N4 becomes easier. But a lower CB position, the electrons will have less potential energy. When the content of g-C3N4 is the same, the g-C3N4/NaTaO3 composite has the best photocatalytic activity. We come the conclusion that the CB position play a more important role than the CB position gap between g-C3N4 and NaTaO3 in the g-C3N4/ABO3 composites. The more negative conduction band is, the higher photocatalytic activity the g-C3N4/ABO3 composites have.KEY WORDS: Tantalate, Niobate, g-C3N4, photocatalysis, super oxygen free radicals, CB position gap;目录第一章 绪论.........................................................11.1 引言.........................................................11.2 半导体光催化剂的光催化原理与过程.............................21.3 半导体光催化剂的改性方法.....................................31.3.1 半导体复合 .............................................31.3.2 离子掺杂 ...............................................31.3.3 贵金属沉积 .............................................41.4 新型光催化剂研究简况.........................................41.4.1 钙钛矿型