沉积物-海水界面的ph两维分布测量方法研究-地球化学专业论文 word格式.docxVIP

Study of Measurement Method of two-dimensional pHdistributions of the sediment–water interface AbstractIntense biogeochemical and mineral dissolution-precipitation reactions in sedimentary deposits generate strong gradients in pH near the sediment-overlying water interface. Sediment pH changes are often dramatic, with ranges of over millimeter to centimeter scales, and can be time-dependent. These distributions reflect not only the acid-base balance determined by early diagenetic reactions but also transport processes such as solute diffusion or advection which govern exchange between sediment and overlying water. The activity of hydrogen ions is a master geochemical parameter reflecting the thermodynamic state of acid-base processes and overall balances between multiple recation and transport processes within natural environments.Suificial marine sediments , in particular , are characterized by complex heterogeneity and sreep gradients in reaction rates, concentration distributions, and mass transport efficiency. In this study , Burial of carbon as CaCO3 and organic matter in marine sediments is a major process in the oceanic carbon cycle and consequently. It is linked to the global carbon cycle, regulating the atmospheric CO2 concentration. Recently the development and application of optical chemical sensors have grown rapidly .In many frequently performed analyses the use of optodes has made measurements feasible which were otherwise difficult to monitor and perform efficiently. Quantifying and understanding the impacts of oceanic uptake of anthropogenic CO2 is an important contemporary problem that has brought intense focus on the ocean inorganic carbon system.In this present study, we developed and investigated the use of a planar optical pH sensor, specifically designed for resolving high-resolution, two-dimensional pH distributions in surface sediments. The pH plate fluorosensor has the potential to greatly improve understanding of mineralization and general