低红外发射率涂层(lirec)的组成结构与性能研究-材料加工工程专业论文.pdf.docx

resin layer thickness can be adjusted, thereby regulating the infrared emissivity of coating. The high attachment rate of the metal pigments can significantly reduce the infrared emissivity of coating. The impact of the infrared transparency of the resin on infrared emissivity of coating reduces significantly when the high attachment rate of Cu flake pigment was elected. Even if the less infrared transparency resin was used, LIREC can be obtained. Therefore, the choice scope of resin adhesive is broadened, and lay a solid foundation for the development of LIREC with good properties.After experimental verification, the infrared emissivity aformula can be used to calculate approximately the infrared emissivity of coating containing flaky particles and can reflect the main factors of the infrared emissivity of the coating.Study of the composition and structure on the mechanical properties of the LIREC:The impacts of polar groups of EPDM-g-MAH, pigment content and resin structure on the mechanical properties of LIREC were analyzed. The results showed that, the mechanical properties of LIREC can be improved by designing the composition and structure of LIREC. 1) Grafting low polarity adhesive with polar groups. The XPS analysis shows that the polar groups of EPDM-g-MAH can form coordination bonds with the metal, significantly improve the mechanical properties of LIREC. 2) Adjusting pigment content. The adhesion of LIREC increased with the increased pigment content, and the hardness first increased and then decreased. The flexibility and resistance to impact strength were significantly reduced for rigid chain of PU-based coatings, while the flexibility and resistance to impact strength of the coating were less affected for the flexible chain resin EPDM-g-MAH. 3) Adjusting resin structure. The flexibility and impact strength resistance of LIREC prepared with EPDM-g-MAH were better than that prepared with polyurethane, while the hardness was somewhat less. The flexibility a