脉冲电沉积镍铬镀层及其防腐性能研究-物理化学专业论文.docx

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2018-05-05 发布于上海
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脉冲电沉积镍铬镀层及其防腐性能研究-物理化学专业论文.docx

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脉冲电沉积镍铬镀层及其防腐性能研究-物理化学专业论文

AbstractElectrodepostionnickel-chromiumalloyhaveattractivepropertiessuchasresistancetocorrosion,goodwearresistanceandhighresistance,itiswidelyappliedforsurfacefinishingandmicrofabrication.Pulseplatingcanbeusedtoimprovethecurrentdistributionandtoaltertheprevailingmasstransportconditions.Itcanalsoservetocontrolthemicrostructureandcompositionofelectrodeposits.Inthispaper,weoptimizedthebathcompositionandachievedsodiumcitrate-acidsystembath.Thefluentofelectrodepositsbychangingpulseon-time,pulseoff-timeandpeakcurrentwasstudied.Weusedscanningelectronicmicroscopy(SEM),atomicforcemicroscopy(AFM)methodstoinvestigatethestructureofsurfacemorphologyandgrainsize,achievedthecoatingcompositionbyenergyspectrum,andevaluatedcorrosionresistanceoftheplatingthroughthepolarizationcurvesandEIStest.Bysurfaceanalysis,electrochemicaltestandhydrogencollection,weconcludethatwhenpulseoff-timeandpeakcurrentareconstant,thecontentofchromiumintheelectrodepositedalloyisgreaterwiththelongerofpulseon-time,thecurrentefficiencyofhydrogenevolutionisbigger,andthegrainsizeissmaller;whenpulseon-timeandpeakcurrentareconstant,thecontentofchromiumintheelectrodepositedalloyissmallerwiththelongerofpulseoff-time,thecurrentefficiencyofhydrogenevolutionissmaller,andthegrainsizeisbigger;whenpulseon-timeandpulseoff-timeareconstant,thecontentofchromiumintheelectrodepositedalloyisgreaterwiththegreaterofpulsepeakcurrent,thecurrentefficiencyofhydrogenevolutionissmaller,andthegrainsizeisbigger.Keyword: carbon steel,pulsecurrent,nickel-chromiumalloycoating, anti-corrosionperformance目录摘要.........................................................................................................................................IAbstract.................................................................................................................................II目录.....................................................................................................................................III1绪论........................