毕业设计（论文）-Al离子掺杂Mn3O4基膜片温敏材料的制备与性能研究1汇.doc

摘 要 本文研究Y2000 Automated x-ray Diffractometer system对样品的相结构进行分析。用型号为SEMI-VICKERS HARDNESS TESTER HV-10的维氏硬度仪的The relationship between log resistivity (logρ) and the reciprocal of the absolute temperature (1/T) of the prepared NTC thermistors was nearly linear,indicative of NTC characteristics. It was found that the electrical resistivity, B 25/85 constant, and activation energy of the thermistors increased with increasing Al 2 O 3 conten热敏电阻电阻率和绝对温度的倒数之间的关系，负温度系数特性Al2O3掺量的增加，样品的B值逐渐增加，且老化后各样品的B值增大，对温度变化的敏感性增强；在热敏常数B为定值时，NTC的电阻率增加。热敏电阻  Abstract In this paper, the preparation、 and properties of FeMnNi1-xAlxO4 have been discussed. Using plasticizer to help shape and high temperature solid state reaction to prepare FeMnNi1-xAlxO4.?With Y2000 Automated x-ray Diffractometer system , the phase structure of the samples were analyzed.?The hardness of the sample was measured by the model SEMI-VICKERS HARDNESS TESTER HV-10 Vickers hardness.?Using homemade equipment to analyze temperature and resistance characteristics of the sample.?The results show that the alumina and other oxides formed solid solution; The relationship between the resistivity of the sample and the reciprocal of absolute temperature is linear, which just showed the negative temperature coefficient characteristics of NTC?; With the Al2O3 content increasing, the value of B gradually increased, and after aging, the value of B also increaseed,which showed the temperature sensitivity of the sample was more strength; When the thermal constant B is constant, NTC resistivity increased with?alumina content increases. Key words: FeMnNi1-xAlxO4 NTC plasticizer solid solution the thermal constant B  目录 摘 要 I Abstract II 目录 III 第一章 综述 1 1．1负温度系数(NTC)热敏电阻材料体系 1 1．1．1 NTC热敏电阻的历史 1 1．1．2 NTC热敏电阻的基本特征参数 2 1．1．3 NTC热敏电阻种类及材料组成体系 3 1．2 NTC热敏电阻的制备 4 1．2．1 粉体制备 5 1．2．2 生坯成型 6 1．2．3 烧结 7 1．2．4 电极制备 7 1．2．5 阻值调整 7 1．2．6 敏化与老练 7 1．3 室温固相反应法制备NTC陶瓷粉体 8 1．3．1 固相反应机理 8 1．3．2 影响因素 9 1．4 NTC热敏电阻的应用及发展趋势 9 1．4．