聚丙烯氢氧化镁poe三元无卤阻燃复合材料的研究-材料学专业论文.docxVIP

起到了异相成核的作用，提高了PP的结晶成核速率；PP及PP/Mg(OH)2/POE体系的晶体生长都为二维盘状生长和三维球状生长并存的方式。由Hoffman-Weeks理论得出POE加入后体系的平衡熔点低于纯PP的。非等温结晶动力学研究表明：Ozawa理论不适用于描述PP/Mg(OH)2/POE复合材料的非等温结晶过程，而修正的Avrami方程和Mo法能够很好的处理此过程。Mg(OH)2和POE提高了材料的结晶成核速率，但是并没有改变PP基体的成核和晶体生长规律。由Hoffman-Lauritzen理论及其推论得到的数据表明POE的加入降低了垂直于分子链方向的折叠自由能和所对应结晶温度时的结晶活化能。关键词：聚丙烯，氢氧化镁，乙烯-1-辛烯共聚物，阻燃，流变行为，结晶动力学Studyon halogen-free flameretardantPP/Mg(OH)2/POEternary compositesABSTRACTWiththedevelopmentofthefieldsofautomobileandelectronicapparatus,themarketdemandofflameretardantpolypropylene(PP)willkeeprapidgrowth.Althoughthehalideretardantsareeffectiveandhavelittleinfluenceonthemechanicalandprocessproperties,theygaveoutheavysmokewithpoisonousandcorrosivegas,whichresultsinhazardstohuman’srespiratorypassageandotherorgans.Withstrongerawarenessofenivormentalprotectionandsecurity,moreandmorecountriesestablishlawtoprohibitorrestrainttheapplicationofhalideretardantsinsomeindustries.Therefore,halogen-free,effectiveandgreenflameretardantmaterialsandthereoftechnologyhavebecomingglobalresearchhotspot.Presently,magnesiumhydroxideiswidelyusedasahalogen-freeretardantforpolymermaterialsduetoitsnon-toxicityandinexpensive.However,magnesiumhydroxideisincompatibilewithpolymerasaninorganicretardantanddisplayslowefficiencyofflameretardant.Generally,itisonlyinthecaseof40-60wt%loadinglevelthatmagnesiumhydroxideproducesaneffectonflameretardant,whichseriouslydeterioratethemechanicaland processproperties.Tosolvethoseabove-mentionedproblems,halogen-freeflameretardantPPwaspreparedbymeltingblendinatwin-screwdextruder,inwhichmagnesiumhydroxideandethylene-co-octanecopolymer(POE)wereusedasflameretardantandtoughener,respectively.Theflameretardance,mechanicalproperties,rheologyandcrystallizationofPP/Mg(OH)2/POEternarycompositeswereinvestigated,theprincipalresultsarelistedasfollowing:OxygenindexandimpactstrengthforPP/Mg(OH)2binarycompositeatthe120wt%loadinglevelofMg(OH)2 were29.5and5.25kJ/m2,respectively;thosevalueswere28.1and36.5 kJ/m2 after the incorporation of 30