添加物对高硫褐煤热解过程中硫、氮气相产物生成的影响-化学工艺专业论文.docx

太原理工大学硕士研究生学位论文发现原煤负载添加物对含硫气体释放的抑制作用大于脱矿物质煤，主要是由于原煤中固有矿物质与添加物共同作用所致:与含硫气体的影响相反，原煤负载添加物含氮气体的释放量高于脱矿物质煤，这主要是原煤中固有的矿物质和添加物的协同作用引起热稳定性相对较高的含氮官能团继续裂解所致。关键词:褐煤，热解，添加物，含硫气体，含氮气体III主太原理T大学硕士研究生学位论文EFFECTOFADDITIVESONTHES-ANDN-CONTAIN卧GGASEOUSPRODUCTSDURINGPYROLYSISOFHIGHSULFURBROWNCOALABSTRACTBrowncoalresourceisrichinChina，butthefeaturesofhighmoisture，highvolatileandlowheat-valuelimitmarkedlyitsutilizationrange.Soitisve可importanttoimprovethequalityofbrowncoalthroughpyrolysis technique.Sulfurandnitrogeninthecoalwillpartlyreleaseintheformofgasousproductsduring the coal pyrolysis，which will cause enviromnental pollution. Itisnecessarytoresearchthereleaseofsulfurandnitrogenduringcoalp严olysis. Thebrown coal丘omX?mengmineinInnerMongoliawasusedas由eexperimental s缸nple. The salts of alkali metal，alkaline earth metal andtransitionmetalwereevenlymixedwithrawcoalanddemineralizedcoal(theinherentrnineralwasremovedbyacid-washing).Theeffectof themineralsand additivesaddedinrawcoalanddernineralizedcoalontheformationofS-containinggasesandN-containinggasesduringtemperatureprogrammedpyròlysiswasstudiedbythefixed-bedexperimentalsetting.Thegaseousproducts仕omcoalpyrolysiswereanalyzedbygaschromatographyandICchromatography.Themainresultsare shownasfollowing:VI.L太原理x二k.字:硕士研究生学位论文Theeffcctofinherent mineralsonthcreleasc ofsulfurand nitrogenduringcoalpyrolysisTheS-containinggasesfrom由epyrolysisofdemineralized coalareobviouslyhigherthanthatofrawcoal，whichshowstheinherentmineralsinXimeng brown coal have the desulfurization capacity and can restrain theformationandreleaseofS-containinggasesduringpyrolysis.Thisactionmainly presentsthetemperaturerange of500-800oC.The s创nemaximumpeaktemperatureofH2SandCOS仕ompyrolysisofdemineralizedcoalandrawcoalshows that the removing ofminerals doesnot affect thesulfurandorganicmatrix in coal.ηle release amount of total N-containing gases 企omdemineralizedcoalpyrolysisisalsohigherthanthat企omrawcoalpyrolysis，butthechangesofHCNandNlI3releasetrendwi由tempera阳re盯edi