废水有机物在废水来源化合物光化学降解中作用.docxVIP

Role of effluent organic matter in the photochemical degradation of compounds of wastewater origin废水有机物在废水来源化合物光化学降解中的作用abstractThe photoreactivity of treated wastewater effluent organic matter differs from that of natural organic matter, and the indirect phototransformation rates of micropollutants originating in wastewater are expected to depend on the fractional contribution of wastewater to total stream flow.经过处理的废水中的有机物的光活性与自然中有机物的光活性不同，源自废水的微量污染物的直接光转化率被估计为取决于废水对总流量的部分贡献。Photodegradation rates of four common compounds of wastewater origin (sulfamethoxazole, sulfadimethoxine, cimetidine and caffeine) were measured in river water, treated municipal wastewater effluent and mixtures of both to simulate various effluent-stream water mixing conditions that could occur in environmental systems. 测定了河水中、市政经过处理废水及两者混合的废水中，源自废水中的4中共同的化合物（磺胺甲恶唑、磺胺地索辛、甲氰米胍、咖啡因）的光解速率，用来模拟发生在环境系统中的多种污水流出后的混合状况。Compounds were chosen for their unique photodegradation pathways with the photochemically produced reactive intermediates, triplet-state excited organic matter (3OM*), singlet oxygen (1O2), and hydroxyl radicals (OH_). 选择化合物用于光化学反应的中间体的独特光降解途径，三线激发态有机物(3OM*),单线态氧(1O2)，羟基自由基(OH_)。For all compounds, higher rates of photodegradation were observed in effluentrelative to upstream river water. 对于全部化合物，下游水中观察到比上游水中更高的光解速率。Sulfamethoxazole degraded primarily via direct photolysis, with some contribution from OH_ and possibly from carbonate radicals and other unidentified reactive intermediates in effluent-containing samples. 磺胺甲恶唑降解主要通过直接光解，此过程OH_有一些贡献，可能来自b包含污水的的样本中碳酸盐自由基和其他未被确认的活性中间体。Sulfadimethoxine also degraded mainly by direct photolysis,and natural organic matter appeared to inhibit this process to a greater extent than predicted by light screening.磺胺地索辛也主要由直接光解降解，而自然有机物，相比于光筛选，在很大程度上更抑制这一过程。In the presence of effluent organic matter, sulfadimethoxine showed additional reactions with OH_ and 1O2. 在有污水有机物存在的情况下，磺胺地索辛显示出了与OH_ 和 1O2额外的反应。In all water samples, cimetidine degraded by reactio