b2o3审审nb2o5审审sro审审bao玻璃陶瓷的制备和性能研究word格式论文.docxVIP

摘要铁电玻璃陶瓷兼具玻璃和铁电陶瓷两种材料的优点，能够制备高性能介电储能材 料，在储能和脉冲领域都有很好的应用前景，从而引起越来越多研究者的兴趣。本论 文通过实验开展了对 B2O3– Nb2O5– SrO– BaO 的改性和研究工作，主要研究内容如下：制备了形态良好的 58B2O3-10Nb2O5-10Li2O 和 58B2O3– 10Nb2O5– 10SrO– 10BaO。两组玻璃陶瓷在不同热处理后的微观结构和介电性能进行了研究。650℃热处理 4 小 时的 58B2O3- 10Nb2O5- 10Li2O 玻璃陶瓷介电性能为： εr =25 ， tanθ =0.008 ， Ev=18.5kv/mm。800℃热处理 4 个小时的 58B2O3- 10Nb2O5- 10SrO- 10BaO 玻璃陶瓷介 电性能为： εr =61， tanθ =0.008， Ev=20.1kv/mm。另外通过掺入稀土元素，分析了 58B2O3-10Nb2O5-10Li2O 和 58B2O3– 10Nb2O5– 10SrO– 10BaO 玻璃陶瓷的析晶模式。研究了 BST，PBLZST 和 BaF2 掺杂对 58B2O3– 10Nb2O5– 10SrO– 10BaO 玻璃陶瓷性能的影响，发现 BaF2 掺杂有利于玻璃陶瓷介电性能的提高。在 BaF2 掺杂 58B2O3– 10Nb2O5– 10SrO– 10BaO- 3BaF2 的基础上系统研究了 Nb2O5, SrO 和 BaO 含量对玻璃 陶瓷介电性能的影响。Nb2O5, SrO 和 BaO 含量对玻璃陶瓷的性能有明显的影响。 58B2O3– 11Nb2O5– 11SrO– 11BaO- 3BaF2 玻璃陶瓷的介电性能最优： εr =116,tanθ =0.011, Ev=25KV/mm,W =0.32J/cm3。e制备不同含量 BaF2 掺杂的 58B2O3– 11Nb2O5– 11SrO– 11BaO 体系，分析了 BaF2掺杂对玻璃陶瓷成核和析晶动力学的影响。实验表明 BaF2 掺杂降低了玻璃陶瓷的析 晶活化能，并且明显地改变了 58B2O3– 11Nb2O5– 11SrO– 11BaO 玻璃陶瓷的微观结构。 BaF2 掺杂明显地提高了玻璃陶瓷的介电常数和抗击穿场强，获得了性能最佳的 58B2O3– 11Nb2O5– 11SrO– 11BaO- 5BaF2 玻璃陶瓷体系： εr =337， tanθ =0.018，eE = 52.7 KV/mm，W =4.14J/cm3。关键词：玻璃陶瓷，储能材料，氟化物掺杂，析晶动力学AbstractDue to good performance of ferroelectric glass ceramics which own both advantages of glass and ferroelectrics, glass ceramic materials are attracting more and more material scientist’s attention. Specially, as the high energy density capacitance, the ferroelectric glass ceramics own huge application value. In ferroelectric glass ceramics, since glass ceramic with high permittivity and high breakdown voltage can meet requirement of power electronics and pulsed power application, a large number of investigations have been started all over the world. In this degree thesis, a series of B2O3– Nb2O5– SrO– BaO glass ceramics were prepared and studied.Transparent 58B2O3- 10Nb2O5- 10Li2O and 58B2O3– 10Nb2O5– 10SrO– 10BaO glass matrixes were prepared by conventional melting. The effect of heating mechanism was both studied in these two glass ceramics. The result proved that high