bini12ti12o3pbtio3基高温压电陶瓷的分析word格式论文.docxVIP

AbstractWith the rapid development of modern science and technology ， piezoelectric ceramics are required to have high Curie temperature for the use in a lot of industrial equipment. However, materials with both high TC and excellent performance are very little. Therefore, the development of new types of high- TC piezoelectric ceramics is imperative. As a new high-TC piezoelectric material, Bi(N i1/2Ti1/2) O3-PbTiO3(BNT-PT) ceramics have attracted much attention because of its high Curie temperature and good piezoelectric ferroelectric properties, exhibiting a good prospect of application. So it has been selected for this study and its high temperature piezoelectric properties have been investigated.Firstly, the optimum PbTiO3 content and sintering temperature at the MPB vicinity of Bi(N i1/2Ti1/2)O3-PbTiO3 ceramics have been studied and the effects of excess A-site ions and different dopants on BNT-PT ceramics density and piezoelectric property have been discussed. The results show that (1-x)Bi(N i1/2Ti1/2)O3-xPbTiO3 ceramics with x=0.45 exhibit the optimal electrical properties when excess Bi and Pb is 1mol% simultaneously, sintering at 1150°C for 2h. The 0.55 Bi(N i1/2Ti1/2)O3-0.45PbTiO3 ceramics possess the optimal piezoelectric and ferroelectric properties with TC=400°C, εm=12000, tgδ=6%(room temperature), Pr=42μC/cm2, EC=41kV/cm, d33=262pC/N。The addition of Mn canreduce the dielectric loss of BNT-PT from 6% to 1%, but the piezoelectric constant d33 decreases rapidly. When Ce addition is 0.4mol%, the dielectric loss of BNT-PT decreases and the piezoelectric constant can still remain 240pC/N, whereas the Cruie temperature decreases from 400°C to 300°C. When doping 1mol% Fe, the density is 7.947g/cm3 and the piezoelectric constant d33 can reach 278pC/N.Then, in order to further improve the electric properties of BNT-PT system,Bi(Mg1/2Ti1/2)O3 and BiFeO3(BF)are selected as a third phase to introduce into BNT-PT. The results indicate that the