cr掺杂对zr2al4c5陶瓷组织及性能影响word格式论文.docxVIP

cr掺杂对zr2al4c5陶瓷组织及性能影响word格式论文.docx

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cr掺杂对zr2al4c5陶瓷组织及性能影响word格式论文

AbstractAbstractZr2Al4C5ceramicshowssuperiorstrength,fracturetoughness,excellentroom andhigh-temperraturestiffnessandchemicalinert.However,itslowbrittleandpoor oxidationresistancearecriticalshortcomingsthatlimititsextensiveapplicationas structure material.Inthispaper, [Zr(Cr)]2Al4C5sampleswerefabricatedbyhot pressingzirconium,chromium,aluminum,andgraphitepowders.Meanwhile, exploredtheeffectofthetemperature,CrcontentandAlcontentonthestructure andpropertiesofmaterials,aswellasCrdopantonfracturebehavior. Muffle furnacewereusedtoexploreintooxidationmechanismof[Zr(Cr)]2Al4C5ceramic throughtheinvestigationofunitareaweightgain,surfacemicroscopicstructureand phasecompositionofoxidationlayerafteroxidation.Phasecontent,microstructure characteristicsandperformancewereanalyzedandcharacterizedintheusageof manyanalyzingandtestingtechnologies.Thecomprehensiveperformanceof[Zr(Cr)]2Al4C5ceramicsisthebestinthe conditionsofsinteringtemperatureof1950 ℃,sinteringpressurefor30MPa,heatpreservationfor1h;Crdopantdonotchangethegrainshape,buttoacertainextent restrainsitsgrowup,makethefracturemodechange;WhenCrdopantcontentis morethansolidsolutionlimitation,CrelementturnstotheCr3C2phase,and increaseswiththeincreaseofthecontentofCr.The oxidation dynamic curve of [Zr(Cr)]2Al4C5 ceramic followed y=a·xbparaboliclawattheoxidationtemperatureof700℃to1000℃.[Zr0.9Cr0.1]2Al4C5ceramic performanced the best oxidation resistancen in the same oxidationconditions throughthecomparisonofunitareaweightgain.AccordingtoXRD analysisforthesurfaceofoxidationlayer,Wefoundthatexternaloxidationlayer mainlycomposedof(Zr,Cr)O2andAl2O3.Theformationofprotectiveoxide (Zr,Cr)O2,andAl2O3,whichcaneffectivelypreventtheoxygentospreadwithin.Keywords:[Zr(Cr)]2Al4C5;ternaryceramic;hot-pressingsintering;mechanical properties;oxidationresistance目录摘要...................................................................................................................IABSTRACT...................................................

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