eu3 tb3掺杂的以lapo4 sio2 tio2不同组合为基质的发光材料的结构与性质分析word格式论文.docx

ABSTRACTRare earth element has good optical, electrical and magnetic properties, among which the optical is especially excellent and cannot be replaced, because of its unique electron shell structure. Therefore, in recent years, the study of Rare earth iron Eu3+and Tb3+ are doped as activator to produce red and green fluorescent material is widely noted. Since luminescent property of activator is closely related to the doped matrix material, changing its matrix material is an important way to study rare earth luminescent material. This paper adopts the sol-gel method, taking La(NO3)3?6H2O, (NH4)2HPO4, Ethyl silicate, and Tetrabutyl titunate as raw material to make a matrix composited of LaPO4-5SiO2,LaPO4-7TiO2,and LaPO4-5SiO2-7TiO2, and then doping Eu3+or Tb3+, to produce rare earth luminescent materials. Use TG-DTA, TEM,XRD, IR and excitation and emission spectra, to characterize and analyze the nature of the morphology, structure, luminous material properties and then study the effect of the material structure, annealing temperature, doping concentration on light-emitting material performance.This study consists of two parts: Part one:Rare earth element both is Eu3+ ions. Select LaPO4-5SiO2, LaPO4-7TiO2,LaPO4-5SiO2-7TiO2 as the composite matrix. The experimental results show that the Eu3+ doped with LaPO4-5SiO2, LaPO4-7TiO2, LaPO4-5SiO2-7TiO2 three kinds of rare earth luminescent material, can emit red light with good monochromaticity and bigger intensity. All of them are good red light-emitting materials, of which LaPO4-7TiO2 doped Eu3+ ion luminescenceperformance are the most excellent. In the study of LaPO4-5SiO2 as the matrix of luminescent material to compare the luminescence properties of pure LaPO4, SiO2 and compound matrix LaPO4-5SiO2, it found that thecomposite substrate material is more advantageous to dope with Eu3+ and its luminous property is more excellent, and also it can save more rare earths. The best annealing te