fe0厌氧微生物耦合体系去除水中2 4 6三氯酚的特性及机理分析word格式论文.docx

AbstractThis paper studied the influence and mechanism of pH value effect “Fe0-anaerobic microbe” system degradation 2,4,6-TCP through analysised the rprotein of 2,4,6-TCP and pH value and corrosion of Fe0 and microorganism activity in different system. In addition we studied the mechanism for degradation of 2,4,6-TCP and the mechanism of bioactivity of microbial promote by Fe0 through other analysise method such as HPLC, GC/MS, SEM and so on. This paper mainly get the following valuable study conclusions:The degradation of 2,4,6-TCP is mainly by microorganisms in “Fe0-microbial” system, Fe0can enhance the rate of degradation for microorganisms.pH value have great influence on the degradation of 2,4,6-TCP in “Fe0-microbial” system. The neutral partial alkali conditions is suitable for biological growth, the best initial pH value for microbial system and “Fe0 – microbial” system were 9.0 and 8.0, respectively 120h and reaction 70h, 2,4,6-TCP can be removaled completely. In Fe0 system because of the corrosion of iron the pH value will increased to 10.0, in that way, the rprotein of 2,4,6-TCP only 20%.pH value has great influence on the activity of iron. In Fe0 system iron could corrode whenthe pH7.0, but when the system pH value 8.0, Fe0 will passivation, couldn’t corrode.The mechanism for degradation of 2,4,6-TCP in different system is different. 2,4,6-TCP couldn’t degradate in Fe0 system, the 2,4,6-TCP may removed through adsorpted by Fe0. The degradation pathways of 2,4,6-TCP in microbial system is: 2,4,6-TCP→2,4-DCP→4-CP. The degradation pathways of 2,4,6-TCP in microbial system is: 2,4,6-TCP→ 2,4-DCP→ 4-CP→ phenol.In “Fe0-microbial” system the synergy of Fe0 and microbial mainly displays in adjustmentfunction of pH value and corrosion of Fe0 and interface enrichment of Fe0. Fe0 and microbial has complementary adjustment function to the system process pH value, they can make the Fe0-microbial system always tends to be neutral process pH value, this will be helpf