fe2b及其共晶合金在液锌中的腐蚀行为word格式论文.docx

Fe2B 及其共晶合金在液锌中的腐蚀行为CORROSION BEHAVIOR OF Fe2B AND Fe-B EUTECTIC ALLOY IN LIQUID ZINCABSTRACTFe2B is a typical interstitial intermetallic compound which has a good corrosion resistance to liquid zinc. However, Fe2B is unsuitable as a kind of monolithic corrosion resistant material owing to its fragility. Pure iron has good mechanical properties, but its corrosion resistance to liquid zinc is so poor. In this study, Fe-B eutectic alloy is designed by combining these two phases. Corrosion-resistant intermetallic compound Fe2B is skeleton filled with tenacious solid solution α(Fe). Eutectic alloy not only has good corrosion resistance performance to liquid zinc, but also good mechanical properties.Matrix/Zn interfaces of Fe2B and Fe-B eutectic alloy are detected by SEM, TEM, XRD and EDS. This paper discusses the processes and mechanisms of corrosionbehaviors of Fe2B and Fe-B eutectic alloy in liquid zinc under 500℃.Molten zinc diffuses into Fe2B matrix along the crystal boundaries. This process can destroy the binding of matrix crystals. Simultaneously, corrosion products are engendered and dissolved by liquid zinc. Directions of Fe2B matrix have an impact on the corrosion process. The corrosion products of Fe2B are FeB, FeZn13 and FeZn8.87. Corrosion of Fe-B eutectic alloy results from interdiffusion of Fe and Zn atoms. Corrosion layer and compound layer emerge, then, they are dissolved by zinc ultimately. The corrosion products of Fe-B eutectic alloy are compounds Fe-B and Fe-Zn, mainly Fe3B and FeZn7. Two corrosion behaviors are different mainly due to content of Fe solution and morphology of Fe2B.KEY WORDS: Fe2B, Fe-B eutectic alloy, liquid zinc corrosion, reactive diffusion, dissolutionii原创性声明本人郑重声明：所呈交的学位论文，是本人在导师指导下，进行研究工作所取得的 成果。除文中已经注明引用的内容外，本学位论文的研究成果不包含任何他人创作的、 已公开发表或者没有公开发表的作品的内容。对本论文所涉及的研究工作做出贡献的其 他个人和集体，均已在文中以明确方式标明。本学位论文原创性声明的法律责任由本人 承担。学位论文作者签名： 日期：关于学位论文版权使用授权的说明本人完全了解河北工业大学关于收集、保存、使用学位论文的规定。同意如下各项 内容：按照学校要求提交学位论文的印刷本和电子版本；学校有权保存学位论文的印刷 本和