nanostructured semiconductor block copolymers π–π stacking, optical and electrochemical properties：半导体纳米结构的嵌段共聚物π–π堆叠，光学和电化学性质_推荐.pdfVIP

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nanostructured semiconductor block copolymers π–π stacking, optical and electrochemical properties：半导体纳米结构的嵌段共聚物π–π堆叠，光学和电化学性质_推荐.pdf

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nanostructured semiconductor block copolymers π–π stacking, optical and electrochemical properties：半导体纳米结构的嵌段共聚物π–π堆叠，光学和电化学性质_推荐

Organic Electronics 8 (2007) 69–75 /locate/orgel Nanostructured semiconductor block copolymers: p–p Stacking, optical and electrochemical properties Stefan M. Lindner, Nadine Kaufmann, Mukundan Thelakkat * Makromolekulare Chemie I, Universitat Bayreuth, Universitatsstrasse 30, 95440 Bayreuth, Germany ¨ ¨ Received 23 December 2005; received in revised form 13 November 2006; accepted 23 November 2006 Available online 19 December 2006 Abstract The structural and optical properties of semiconductor block copolymers containing triphenylamine as hole transport material and perylene bisimide as dye and electron transport material are reported. The polymers were prepared by nitr- oxide mediated controlled radical polymerisation and characterized with GPC, DSC, and TGA. The electrochemical prop- erties as determined by cyclic voltammetry show the HOMO and LUMO values of the block copolymers to be 5.23 eV and 3.65 eV, respectively. The perylene bisimide units aggregate by p–p stacking which could be analyzed with wide- angle X-ray scattering. The absorption and ﬂuorescence properties of the perylene bisimide polymers and monomers in solution and ﬁlm were investigated. It could be shown that they are strongly inﬂuenced by intramolecular coupling between diﬀerent perylene bisimide units in polymers. The block copolymers exhibit a microphase separation on a nano- meter scale with a constant perylene bisimide domain width of 13 nm and lengths of up to several micrometers. 2006 Elsevier B.V. All rights reserved. PACS: 84.60.Jt; 87.15.Nn; 73.61.Ph; 78.66.Qn Keywor