激光电子散斑干涉技术分析典型金属的腐蚀行为-analysis of corrosion behavior of typical metals by laser electron speckle interferometry.docx

AbstractThe technique based on Electric Speckle Pattern Interferometry (ESPI), Chronoamperometry, Electrochemical Impedance Spectra (EIS) and linear sweep voltammetry was applied to study the corrosion behavior of carbon steel in NaHCO3-NaCl-CaCl2 solution. An ESPI based technique for in situ and accurate observation of pitting susceptibility of 304 stainless steel in NaCl solutions is reported in this paper. The main results are as following:The influence of carbon steel Corrosion behavior under the Ca2+ ion of differentconcentrations was investigate by analyzing the average corrosion rate of chronoamperometry, statistically analyzing the appearance of etch pits and analyzing the Charge transfer resistanc of EIS. The results indicated that, the Ca2+ ion on 0~640mg/L makes a inhibition effect of carbon steel corrosion, When Ca2+ ion concentration was 640mg/L, Chronoamperometry measured average corrosion rate for 3.253E-4A/cm2, electrochemical impedance measured the charge transfer resistancefor 29.480 kΩ·cm2, The degree of pit corrosion intensity is 2.791, the corrosionbehavior of carbon steel is the slightest.Through analysis the Pitting corrosion inductions time to help identify specimens pitting resistant. When the solution without Ca2+ ions, the induction time is 88s and the pitting corrosion resistant was the worst. When Ca2+ ions concentration is 0~640 mg/L,the pitting induction time increases with the Ca2+ ions concentration and the pitting risistant increase gradually. When Ca2+ ions concentration is 2560 mg/L, the pitting induction time is 93s less than 640mg/L which pitting induction time is104s. Explain that carbon steel pitting resistance is reduced, but stillis greater than solution with no Ca2+ ions.The pitting corrosion sensitivity of 304 stainless steel in NaCl solution under different Cl- concentration 、temperature and pH was studied by Eb′ which wasmeasured by ESPI combining dynamic potential linear scanning and EIS. Research shows that, Time con