季铵盐阳离子表面活性剂及其复配体系形成有序聚集体流变性能-rheological property of ordered aggregate formed by quaternary ammonium salt cationic surfactant and its compound system.docx

链表面活性剂 R14HTAB 和双子表面活性剂 n-3(OH)-n(2Cl)体系的影响。研究表明，盐的加入使单纯表面活性剂溶液的粘弹性显著增强，有机盐对表面活性剂的作用主要 有：（1）盐析效应；（2）氢键作用；（3）静电作用；（4）空间效应；（5）长疏 水链间的疏水作用。并且随着盐的浓度的变化，溶液的零剪切粘度形成了复杂的流变 曲线，符合 Maxwell 流体类型，具有单一松弛时间，因此可以用 Maxwell 方程处理 各类曲线，得到不同的流变参数，根据表面活性剂和添加剂之间的相互作用，结合其 他的测量手段，以解释溶液的宏观及微观性能。关键字：阳离子表面活性剂；有机盐；流变性质；蠕虫状胶束ABSTRACTQuaternary ammonium cationic surfactants are extensive applyed in food, cosmetics, medicine, etc. The rheological properties of the solution or dispersion system is closely related to their microstructure and the interaction among them, its important physical and chemical properties in the process of their application must be clear. As a result, the rheological properties of surfactant micelles become an important basic theory and widely used in all aspects of the actual articles for daily use and industrial. In the surfactant solution, surfactant molecules combined in ordered molecular aggregation by hydrophobic, such as micelle, vesicle, lamellar liquid crystal and cubic crystal, etc. The worm-like micelles which due to its surface activity, viscosity and excellent shear dilution performance, become the focus of the research area. In addition, the shape and their microstructure of the aggregate is decided by the composition of surfactant system, molecular structure and the concentration, the rheological properties of surfactant solution can greatly improve by joining additives, such as cosurfactant, organic salt, inorganic salt, polymer.As a part of the project supported by National Natural Science Foundation (No.21001061), our work is as follows:（一）A 2-hydroxypropoxy group was inserted at the junction between the headgroup and the alkyl chain of quaternary ammonium salts. This group promotes a bent configuration for the alkyl chain relative to the ammonium headgroup, as compared tothose without the 2-hydroxypropoxy group. We examines the rheological behavior of different concentrations of pure surfactant 3 - alkoxy - 2 - hydroxypropyl trimethyl ammonium