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介孔不饱和聚酯的合成与性能分析-synthesis and property analysis of mesoporous unsaturated polyester
AbstractTheunsaturatedpolyesterresin(UPR)withitsoutstandingpropertiessuchashighstrength,lightweight,lowcost,electricalinsulationandsoon,hasbeenwidelyusedinexplosion-proofelectricapparatus,low-voltageapparatus,automotiveelectronics,aerospaceelectricalandotherfields.However,someshortagessuchaspoorthermalandtribologicalpropertieshaverestrictedtheuseofUPRinsomehighperformanceapplications.Therefore,propertieswithhighstrength,highwearresistanceandhighheatresistancearestilltheresearchhotspotinthestudyofmodificationfortheunsaturatedpolyesterresin.Mesoporousmolecularsieve,anovelnanoscalematerialswhichpossesalargespecificsurfaceareas,atunableporesizes(2~50nm)andtheexcellentadsorption,providethepossibilityofincorporatingdiverseorganicguestspeciesfillingintotheorderedmesoporousstructures,forminganorganic-inorganicinterpenetratingnetworkstructure.Thentheadhesionstrengthoftheinterfacewillbeimprovedandwecouldprepareapolymercompositeresinwithhigherperformance.Inthispaper,themesoporousmaterials(MCM-41andSBA-15)/unsaturatedpolyestercompositeresinwaspreparedthroughin-situpolymerization.Meanwhile,theeffectsofdifferentcontentsofmesoporousmaterials,dispersionmethod,speciesofmesoporousandtemplateagentonthepropertiesofunsaturatedpolyestercompositeresinwerefurtherstudied.Detailedresearchresultsareasfollows:1、ThemesoporousmaterialsMCM-41/unsaturatedpolyestercompositeresinwaspreparedthroughin-situpolymerization.Theresultsshowedthatduringthein-situpolymerizationtheorderingofMCM-41decreasedanditsdiameterreducedfrom4.41to2.73nm,whichdemonstratedthattheUPchainpenetratedthroughthemesoporouschannelofMCM-41.ComparedwiththepureUP,theTd,5valueoftheMCM-41/UPcomposites(MCM-41contentsbetween1~3wt%)wereall30℃higher.WhenthecontentofMCM-41was2wt%,theimpactstrengthandflexuralstrengthoftheMCM-41/UPcompositereachedthemaximumvalue,6.73KJ/m2and87.13MPa,respectivelyincreasedby39.34%and4.9%comparingwiththeneatUPcomposites.Meanwhile,themasswearingof2%MCM-41/UPcompositewas88mg,decreasedby37.4%comparingwiththeneatUPc
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