浸没式超滤膜处理高藻水原水的研究——以黄河库水为例-study on treatment of raw water with high algae water by immersion ultrafiltration membrane - a case study of yellow river reservoir water.docx

摘要采用浸没式超滤膜对引黄水库夏季高藻水进行中试试验研究，考察在夏季高 藻期超滤膜对引黄水库水处理效果和膜污染控制情况，探讨超滤技术在山东某水 厂饮用水处理中应用的可行性，为超滤膜处理工艺大规模应用于饮用水生产提供 一定的实践依据和技术参考。试验表明混凝沉淀-气浮移动罩滤池-超滤工艺出水水质稳定，超滤膜对有机 物指标具有一定的去除效果，对 CODMn、UV254、TOC 的平均去除率分别为 12.5%、 8.57%、19.8%；对浊度、颗粒物、藻类、微生物具有良好的去除效果，其中超 滤膜出水浊度不受进水水质影响，基本稳定在 0.1NTU 以下，粒径大于 10μm 的 颗粒几乎被完全去除，超滤膜几乎能 100%去除藻类，运行期间超滤膜出水没有 检测出大肠菌群；对氨氮、铁铝、溴味的去除效果不太明显。考察了过滤周期、中间气冲时间、气水比、通量、排污时间对浸没式膜污染 的影响。结果表明在高温高藻期采用过滤周期 1.5h、中间气冲 30s、气水比 4:1～ 5:1、通量 30 L/(m2·h)、排污时间 25s～30s 的工况能较好的减缓膜的污染；化学 清洗能较好的恢复膜通量;并对超滤系统成本进行了简要分析。本试验还将超滤膜与臭氧活性炭、常规工艺对主要污染物指标的去除效果进 行了简要比较，并讨论了超滤技术在自来水厂中应用的优势。关键词：浸没式超滤膜，引黄水库水，运行参数，膜污染AbstractA pilot study on the treatment of algae-laden from Yellow River reservoir was conducted by immersed ultrafiltration, the effect of contaminants removal by immersed membrane and the controlling of membrane fouling were investigated; studying the possibility of application of ultrafiltration technology in a certain WTP of Shandong province; providing the necessary technology support for the full-scale applications of ultrafiltration technology in drinking water treatment.It was proved that the quality of treated water after coagulation-sedimentation-floatation movable hood filter-immersed ultrafiltration process is stable; the ultrafiltration membrane had a certain effect on the removal of organic matter, the average removal rate of CODMn,UV254,TOC is separately12.5%、8.57%、19.8%; therewas good removal efficiency for turbidity, particles, algaes and microbe, the change of raw water had little effect on filtrate turbidity which is stable with 1ess than 0.10NTU, particles with size more than 10μm and algaes could be completely removed; the coliforms were never detected in the treated water; ultrafiltration membrane had little effect on the removal of nitrogen, iron, aluminum,2-MIB and Geosmin.The effects of different filter cycle, aeration time, gas-water ratio, different flux and the discharging time on membrane fouling were investigated. The results showed that when the raw water