浸渍法制备纳米niysz阳极的分析-analysis of nano niysz anode prepared by impregnation method.docx

摘 要长的速率方程，得出 NiO 晶粒在多孔的 YSZ 骨架表面生长的活化能，并研究了烧结的微观过程。通过测试不同预烧温度和预烧时间下的阳极电导弛豫，发 现 NiO/YSZ 阳极前驱体在 700℃的预烧温度下保温时间设为 1h 时其初始电导 率为 307.6S/cm，恒温测试 10h 后，其电导率衰减到 101.1S/cm，相比其他制 备条件其阳极电性能最好。本文还分析了木薯粉和面粉作为造孔剂对浸渍法制备阳极的影响。研究 发现，木薯粉作为造孔剂制备的孔结构有利于 NiO 在 YSZ 晶面上的附着及生 长，但它在浸渍过程中的渗透性不好，而面粉作为造孔剂的孔结构虽有利于 溶液浸渍和气体扩散，但它不利于 NiO 在 YSZ 表面的附着。为改善电池的输 出性能，结合了这两种造孔剂的优点，分别采用了直接混合和分层的办法 将 木薯粉和面粉混合作为造孔剂，制备单电池并比较其输出性能，结果显示： 通过分层的办法制备的单电池最大输出功率可达 400 mW?cm-2，好于直接混合 法和单独以木薯粉或面粉为造孔剂的单电池。关键词： Ni/YSZ 纳米阳极；浸渍量；烧结；稳定性；预烧过程；造孔剂AbstractSolid oxide fuel cell (SOFC), as a kind of cleaning, high efficiency fuel cell, is very promising for the next generation power sources because of its efficiency of up to 80%. However, there are still several obstacles need to be overcome before its real application such as high temperaute operating, high internal resistance and low power density at reduced temperatures. In order to resolve these problems, the following two aspects need to be considered carefully: on one hand, developing new electrolytes with higher ionic conductivity and electrode materials with higher electrochemical activity at reduced temperatures.On the other hand, changing preparation method to improve the microstructure of electrolyte and electrodes and thus to improve the performance. Generally, the above-mentioned approaches are combined to get optimized performance.This paper focus on fabrication of nanometer Ni/YSZ anode with impregnation method, which could improve anode performance b y changing traditional anode micro-structure.. At first the sample mixing of YSZ andpore-forming material was sintered at 1400℃ to get porous-YSZ skeleton, then itwas impregnated with an mixing aqueous solution of Ni(NO3)2·6H2O and urea by capillary force, finally, it was fired and reduced blow 1000℃ to form Ni/YSZanode. The Ni was introduced to anode after the high temperature sintering of YSZ skeleton via impregnation. By this way, we can get anode with nano-sized Ni active particles through low