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2018-05-29 发布于上海
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可控光-controllable light.docx

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可控光-controllable light

AbstractAlltheworksofthisresearchweresupportedbytheXinjiangScienceandTechnologyDepartmentDesertificationCombatSeriesofDripIrrigationFertilizerIndustryProject.Inthisstudy,twokindsofthermalcatalystNiCoMnO4andNTCwereselected,whichwereputtingintothepolyethylenegroundfilmforfarm,studiedsystematicallymembranethedegradationpropertyunderdifferenttemperature,illuminationtimeandatdifferenttemperatureandillumination.Meanwhileinordertorealizethecontrollabilityofmulchbycompoundwiththreekindsofcatalysts.Itwasthehopethatthisresearchmayoffersomereferencesandguidancefortheindustrialmanufacture.Themainresultswereasfollows:TwokindsofcatalystsinthecyclicvoltammogramsshowedthattheNiCoMnO4andNTCelectrodereactioninphosphatebufferwasdiffusioncontrolledandtheprocesswasquasi-reversibleanditdidn’tchangeindifferenttemperature.TheCVsofelectro-catalyticoxidationofhydrogenperoxideatthetwocatalystelectrodeshowedthatthecatalyticeffectsonhydrogenperoxidewereirreversible.Catalyticefficiencywashigherwiththetemperatureraise.Indealingwithatemperatureof60℃REDOXpeakpotentialdifferencereachesmaximumvalue，thepotentialdifferenceraisefrom0.212Vto0.337V.Thecatalyticefficiencywashighestwhen0.5%NiCoMnO4andNTCwereaddedinthefilm,theretentionrateofelongationdeclineto10%at60℃afterdisposing42dand87d,degreeofcrystallinitywasascendfrom34.32to38.59、from34.1to37.46.Carbonylabsorptionpeakappearedintheinfraredspectrumatthetimeofoxidationdegradationof90d,theabsorptionpeakwasbecomingmoreandmorestrongwiththeextensionofprocessingtime.TheSEMshowedthatafterdegradationthesurfaceofthefilmbecamerough,maximumheightdifference.NiCoMnO4’CatalyticefficiencywashigherthanthatNTC’,soNiCoMnO4wasamoreexcellentcatalyst.Underthehighlightsof19W*6with192h,60℃,NiCoMnO4andNTCfilm’weightlessnessrateunderlowlightintensityincreasedby0.92%and2.11%respectively.Infraredspectrumshowedthrough60℃highlightsstrongprocessingofdegradablemulchingfilmhadmoreoxidationproduct.Surfacemorphologyofsamplesundertheconditionofstrongspecularandhightemperaturewhenhandling