拉应力对x80管线钢在酸性土壤环境中电化学行为影响-effect of tensile stress on electrochemical behavior of x80 pipeline steel in acidic soil environment.docxVIP
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拉应力对x80管线钢在酸性土壤环境中电化学行为影响-effect of tensile stress on electrochemical behavior of x80 pipeline steel in acidic soil environment
AbstractX80pipelinesteeliswidelyusedinthefieldofoilandgastransportationin21thcentury.TheX80steelsufferedstresscorrosioninserviceundercombinedeffectofstressandcorrosiveenvironment.Alotofresearcheshavebeendoneabouttheinfluenceofstressoncorrosionbehavior,butabasicconsensushasnotbeenconcludedonitsinfluencemechanism.Therefore,thereisanobvioustheoreticalandpracticalsignificancetostudytheinfluenceofstressonelectrochemicalbehaviorofX80steelinacidsoilenvironment.Inthispaper,thecorrosionelectrochemicalbehavioroftensilestress(0MPa、100MPa、200MPa、300MPa、400MPa)onthethreemicrostructuresofX80pipelinesteelwerestudiedbyelectrochemicalmeasurements.Thesensitivityofthreemicrostructurestostressaswellastheinfluencerulesoftheelectrochemicalactivityandtheprotectivenessofcorrosionproductfilmwerealsodiscussed.Themainconclusionsareasfollows:ThecorrosiontendencyincreasedwhentensilestressappliedonX80steel.Thewaterquenchingmicrostructurewasmostsensitivetostress,thentheoilquenchingmicrostructure.Electrochemicalimpedancespectrumwascomposedoftwoandahalfarcforthreedifferentmicrostructures.Astensilestressincreased,thereactionactivityoftheoriginalmicrostructureofX80steelincreased,thereactionresistance(Rct)valuebecamesmallerbydegrees,thecorrosionproductfilmresistance(Rf)firstlydecreasedandthenincreased,andcorrosioncurrentdensitieschangedconversely.TheoriginalofwaterquenchingandoilquenchingRctdecreasedandRfincreasedcontinuallywithincreasingstress.Theanodicdissolutionoccurpreferentiallyatthe“exposure”locations,resultinginaconsequentpromotionofcorrosionactivityandpromotingtheaccumulationofcorrosionproductontheonehand.Ontheotherhand,tensilestressbrokecorrosionproductfilm,theprotectivenesstomatrixmetaldecreased;thewaterquenchingmicrostructurehademinentreactionactivityduetohighdislocationdensity,theoilquenchingmicrostructuretooksecondplace,theminimumwasoriginalmicrostructure.Asincreasedoftensilestress,thenoisesignaloforiginalmicrostructurefirstlyIIIdecreasedandthenincreased,thenoiseresistancechangedconversel
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