锂硅粉吸附除磷及稀土改性性能分析-analysis of adsorption phosphorus removal and rare earth modification performance of lithium silicon powder.docx

摘要磷是引起水体富营养化最主要因子，对水体进行除磷处理，具有重要的客观需求。目前，吸附除磷是常用的方法，吸附材料的选择对吸附除磷的效果有着重要的影响。锂硅粉是冶炼废弃物，具有多孔等特性，为此本论文开展以锂硅粉吸附磷性能研究，既能除去水体中的磷，也可将废弃物得到应用。论文以锂硅粉为原料，模拟含磷废水为研究对象，进行锂硅粉及锂硅粉改性吸附除磷吸附特性研究，并对实际废水进行吸附研究，通过研究得到如下结论：（1）锂硅粉对磷的吸附过程是一个快速吸附过程，对浓度为2mg/L的模拟废水，锂硅粉的投加量达到9.6g/L,能够在90min内达到吸附平衡，磷的吸附率为94%。（2）锂硅粉对磷的吸附量为1.166mg/g，采用Freundlich等温吸附模型和拟二级动力学模型能较好的模拟锂硅粉对磷的吸附过程。（3）通过硝酸铈改性后的锂硅粉，在反应60min，投加量为4.8g/L时达到吸附平衡，吸附量为10.89(mg/g)，相对于未改性的锂硅粉，投加量减少一半，最大吸附容量提高了接近10倍，说明改性大大提高了锂硅粉的吸附除磷效果。（4）锂硅粉改性后对磷的吸附过程，可用Freundlich模型和拟二级动力学模型进行描述。（5）改性后的锂硅粉通过7次解析再生后，对磷的吸附性能降低了13%，第七次解析再生对磷的吸附性能下降较多。（6）通过对西华大学校园水池水体的除磷处理，说明改性锂硅粉具有较好的吸附除磷效果，具有实际应用的价值。关键词：锂硅粉；磷；吸附；硝酸铈；改性AbstractWatereutrophicationismainlycausedbynitrogenandphosphorus,atmosttimephosphorusisbelievedasthecorefactor,whichrequiresprocessingtoreducetheconcentrationofphosphorusinthewater.Currently,thecommonmethodisabsorption,inwhich,adsorptionmaterial’schoiceforthephosphorusadsorbhasasignificantimpact.Inthisstudy,useofindustrialwasteresiduelithiumfumewhichproducedafterextractionforthestudy,andithasmanyporous.Inthispaper,Lithiumsiliconpowderisuseasrawmaterial,Simulatedphosphoruswastewaterresearchasobject,lithiumandlithiumfumesilicafumemodifiedphosphorusadsorptionAdsorptioncharacteristics,andactualwastewateradsorptionstudiedandachievedgoodresults.Adsorptionofphosphorusbythesiliconpowderisafastadsorptionprocess.Ontheconcentrationof2mg/Lofwastewater,thedosageoflithiumfumereachesto9.6g/Landreachadsorptionequilibriumwithin90min.Pseudo-secondkineticmodelcancapableofsimulatinglithiumphosphorusfumeadsorptionprocess.lithiumfumetheoreticalphosphorusadsorptioncapacityis1.166mg/g.Freundlichisothermequationisfitfordescriptionoftheadsorption;Pseudo-secondkineticmodelcancapableofsimulatinglithiumphosphorusfumeadsorptionprocess.Cebylithiummodifiedsilicafume,just60minbythereaction,andthereductioninthedosageisnotmodifieddosingthanhalfof4.8g/L,willbeabletoreachadsorptionequilibriumthemaximumadsorptioncapacityof10.89(mg/g),unmodifiedwithrespecttolithiumsiliconpowder,themaximu