锂离子电池 lini0.5mn1.5o4正极材料和哌啶型 离子液体混合电解液的研究-study on lini 0.5 mn 1.5 o4 cathode material and piperidine ionic liquid mixed electrolyte for lithium ion batteries.docx

持率较纯有机溶剂电解液高，循环性能得到改善，其中PP13TFSI的含量为10%时，效果相对较好。关键词：LiNi0.5Mn1.5O4；Al掺杂；正极材料；喷雾干燥法；离子液体；流变相法；电化学性能IIAbstractSpinelLiNi0.5Mn1.5O4cathodematerialhasabroadprospectforLi-ionbatteryusedinelectricvehiclesbecauseofitshighvoltage，highenergydensity,longlifeandnoharmtoenvironment.However,thematerialhassomedefectsinpracticalapplication,suchastheimpurityandthepoorcycleperformance,improveandwithoutthesuitablehigh-voltageelectrolyte.Therefore,inthispaperthepreparationandmodificationofLiNi0.5Mn1.5O4cathodematerialwerestudiedandthepiperidineionicliquidsbasedmixedelectrolyteweredeveloped.LiNi0.5Mn1.5O4cathodematerialwaspreparedbyrheologicalmethodwithMn(CH3COO)2·4H2O,Ni(CH3COO)2·4H2OandCH3COOLi·2H2O.thecalciningtemperature,sinteringtimeandlithiumcontentwereoptimized.Thestructure,morphologyandelectrochemicalpropertiesoftheLiNi0.5Mn1.5O4cathodematerialwerecharacterizedbyX-raydiffraction,scanningelectronmicroscopeandcharge-dischargetest.Theresultsshowedthatthematerialwith5%excessofLithiumcontent,calcinedat850℃about6hourswasconfirmedtothebestinviewofIIIelectrochemicalperformance.Itsspecificdischargecapacitywas127.1mAh/gat0.1Cdischargerate,andafter50cyclesthecapacityretentionwas95.4%.LiNi0.5-xAl2xMn1.5-xO4cathodematerialwaspreparedbyspray-dryingmethodwithMn(CH3COO)2·4H2O,Ni(CH3COO)2·4H2O,CH3COOLi·2H2OandAl(NO3)3·9H2O.Thestructure,morphologyandelectrochemicalpropertiesofLiNi0.5-xAl2xMn1.5-xO4cathodematerialwerecharacterizedbyXRD,SEMandcharge-dischargetests.TheresultsshowedthattheLiNi0.5-xAl2xMn1.5-xO4(x=0.05)samplehadthebestelectrochemicalperformance,Itsspecificdischargecapacitywas123.5mAh/gat0.1Cdischargerate,andafter50cyclesthecapacityretentionwas98.6%,andshowedgoodcyclingability.Roomtemperatureionicliquids(RTILs)ofN-methyl-N-ethyl(propyl,butyl)piperidiniumbis(trifluoromethanesulfonyl)imide(PP12（3,4）TFSI)weresynthesizedwithtwostepconstantrefluxmethodandthenmixedelectrolyte1mol/LLiPF6(PP12（3,4）TFSI)+ethylenecarbonate(EC)+dimethylenecarbonate(DMC)withorganicsolventEC,DMC.TheresultsfromNucl