立方aln薄膜的激光分子束外延生长及其光学性能分析-laser molecular beam epitaxial growth of cubic aln thin films and its optical properties analysis.docxVIP
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立方aln薄膜的激光分子束外延生长及其光学性能分析-laser molecular beam epitaxial growth of cubic aln thin films and its optical properties analysis
导体。基于薄膜的透射光谱,采用BCC法计算得到薄膜在不同工艺参数下的声子能量值在0.120~0.125eV之间,这对应于其横向光学声子能量。薄膜的禁带宽度值在4.3~4.5eV之间,随着晶格常数畸变量的增加,禁带宽度降低。4.根据第一性原理,采用MS软件对立方AlN的能带结构和状态密度进行了模拟计算。计算结果表明,立方AlN的导带底与价带顶不处于同一K点,验证了其为间接带隙半导体。计算得到立方AlN的禁带宽度为4.392eV,与实验值基本一致。关键词:激光分子束外延亚稳立方AlN薄膜显微组织结构界面结构光学性能GROWTHANDOPTICALPROPERTIESOFCUBICAlNFILMSDEPOSITEDBYLASERMOLECULARBEAMEPITAXYABSTRACTTheIII-VsemiconductorcubicAlNfilmisbecomingapromisingoptoelectronicandmicroelectronicmaterialforitsexcellentproperties.However,cubicAlNfilmexhibitspoorqualityduetoitsmetastablenature,andthustheenergybandstructure,opticalandelectricalproperties,andotherbasicphysicalpropertiesareseldomreported.Inthispaper,cubicAlNfilmswerepreparedonMgO(100)substratesbylasermolecularbeamepitaxytechnique.Thecrystalstructure,surfacemorphology,interfacialstructureandopticalpropertiesofcubicAlNfilmsdepositedatdifferentprocessparameterswereanalyzedsystematically.Meanwhile,theenergybandstructureanddensityofstatesofcubicAlNweresimulatedusingthefirstprinciples.Theresultsareasfollows:Cubicrock-saltAlNfilmswiththesinglepreferredorientationweredepositedonMgO(100)substratesbylasermolecularbeamepitaxytechnique.TheorientationrelationshipofcubicAlNfilmandMgOsubstrateisAlN(100)[100]//MgO(100)[100].CubicAlNfilmsshowtheexcellentcrystallinityandsurfacemorphologyatthesubstratetemperatureof700℃,thepulsedlaserenergyof125mJ·p-1,thenitrogenpartialpressureof0.8Pa,andtheannealingtemperatureof700℃.ForthelatticemismatchbetweenMgOsubstrateandcubicAlNfilms,thereexistscertainmisfitstressinthecubicAlNfilms.TheinterfacebetweencubicAlNfilmandMgOsubstrateisclearandsmooth.AdjacenttotheMgOsubstrate,athinstrainlayercausedbythestrainrelaxationoflatticemismatchisobserved.AcoherentinterfaceisformedattheinterfacebetweencubicAlNfilmandMgOsubstrate.However,latticedefects,suchasmisfitdislocationanddisorderedstructure,arealsofoundinthefilmandattheinterfaceasaresultofthemisfitstress,andthedefectdensityisextremelyhighintheinterfaceregion.CubicAlNfilmsexhibithightransmittanceinthevisibleregion.Nea
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