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硫化胶老化性能的fox h函数研究-study on fox h function of aging property of vulcanized rubber
AbstractPolymershavebeenwidelyusedinindustry,agriculture,advancedscienceandtechnologyandourdailylife.Themainreasonisthatithasaseriesofgoodmechanicalproperties.However,duringthecourseofmachining,storing,transportandusing,mechanicalpropertiesofpolymersusuallyresultinagingowingtocompositeeffectofinsideandoutsidefactors.Viscoelasticityisrepresentativemechanicalcharacteristicsofpolymer.Fractionalcalculuswasimportedintotheconstitutiveequationinthefieldofviscoelasticity,thatmadeagreatdevelopmentintheviscoelastictheory.Thesemodelspossessasmallnumberofsingleelementsandparameters,butcandescribecomplexviscoelasticbehaviorverywell.Bythemethodofmechanicsofcontinuousmedia,westudypropertiesofpolymerduringagingusingatooloffractionalcalculus.Thisstudyhastheimportanttheoreticalvalueandpracticalsignificanceforfindingouttherelationbetweenpropertyandstructureofpolymer.ThestressrelaxationcharacteristicsofthegeneralizedfractionalMaxwellmodelaredetailedlyanalyzedinthisthesis.WebrieflyintroducetheexperimentaldescriptionandmeasurementofpropertiesofthestressrelaxationandcompressionsetofVRduringaging.Basedonexperiment,startingwiththefractionalviscoelastictheory,throughreasoning,hypothesisandanalogy,amathematicalmodelisputforwardtodescribethedegradationruleofpropertiesofthestressrelaxationandcompressionsetofVRduringtheisothermalthermo-oxidativeagingbymeansofFox-Hfunction.ThemodelisrespectivelyusedtosimulatedataofstressrelaxationcoefficientandcompressionsetratioofNBRandCRduringthermo-oxidativeagingwiththechangingofthetime.MacroscopicaldifferencesofthepropertyofsamplearemainlyrepresentedbyτandE0,whereasαandβreflectthedegeneratecharacteristicsofitspropertyinthedifferentstage.ThemodelisusedtosimulatedataofstressrelaxationcoefficientofEPDMinovenduringacceleratedagingwiththechangingofthetime.Logarithmofrelaxationtimeofsampledecreaseslinearlywiththeincreaseoftemperature.Basedonexperiment,startingwiththefractionalviscoelastictheory,throughanalogy,amathematicalmodelisputforwardtodescribethestressrelaxat
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