keggin结构硅钨酸导向合成光电纳米材料分析-analysis of kegg in structural silicotungstic acid - guided synthesis of optoelectronic nanomaterials.docx

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2018-05-28 发布于上海
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keggin结构硅钨酸导向合成光电纳米材料分析-analysis of kegg in structural silicotungstic acid - guided synthesis of optoelectronic nanomaterials.docx

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keggin结构硅钨酸导向合成光电纳米材料分析-analysis of kegg in structural silicotungstic acid - guided synthesis of optoelectronic nanomaterials

AbstractThesynthesisofopticalandelectricalnanomaterialsisagrowingresearchfieldinnanotechnology.Inthisstudy,opticalandelectricalnanoparticlescontainingCuI,CdS,Ag2SeandHgSeetc.weresynthesizedwithKegginstructuretungstosilicateacid(TSA)asreducingagentandtempletagent.Varioussynthesismethodssuchaslightradialization,gasdiffusion,hydrothermaltreatmentandsolid-phaseprocesswereadopted.Theorientedgrowthmechanismandopticalandelectricalpropertiesofthepreparednanoparticleswerealsostudied.Themainresultscanbesummarizedasfollowing:CuInanocrystalswithdiamond-shapedandplatelet-shapedmorphologiesweresynthesizedwithTSAasreducingagentunderUV-irradiation.KIandI2wereservedasiodineorigin,respectively.ThegrowthmechanismofCuIcrystalswasproposedthattheformationofdiamond-shapedCuInanocrystalsisduetohomogeneousnucleationinthesupersaturationofCu+andI-,andtheformationoftheplateletscanbeexplainedbyatropismgrowththeory.Comparedtotheotherreducingagent,suchasNaBH4,whichdirectlyreducedCu2+toCu0,TSAhasanappropriateabilityforthereducingofCu2+toCu+.ThegrowthprocesseshavebeenmonitoredbyUV/VisabsorptionandbyroomtemperaturePLspectra.ThePLpropertiesofCuIcrystalswererelatedtothesurfacedefectoftheir(111)planes.Diamond-shapedCuIcrystalshaveabetterelectricpropertythanplatelet-shapedCuIcrystals.Anovelapproach,whichcombinedgasdiffusionandhydrothermalmethod,wasdesignedforthesynthesisofcadmiumsulfide(CdS)assemblieswithkeggintypeTSAasscaffold.ItisfoundthatslowdiffusionrateofH2Sgasleadstoaflowerlikemorphologyandfastdiffusionrateleanstoasphericalmorphology.TheevolutionofCdSmicrospheretoflowerlikestructurecanbemodulatedbytuningthediffusionrateofH2Sgas,whichisdominatedbythereactiontemperature.TheopticalpropertiesoftheflowerlikeCdSassembliesinthetemperaturerangeof35-300Kwerestudied.ItfoundthatthePLintensitywasincreasedwithdecreasingtemperature.Furthmore,severaldifferenttypesofaminoacidsandakindofpolyelectrolytewereusedasmodificationagentsforTSA.ThecomplextemplatesareusedtocontrolsynthesisofCdSnanostructureswithvariousmorph