电化学阻抗研究形核机理.docVIP

电化学阻抗研究形核机理 导读：就爱阅读网友为您分享以下“电化学阻抗研究形核机理”资讯，希望对您有所帮助，感谢您对92的支持! Electrochemical impedance spectroscopy study of the nucleation and growth of apatite on chemically treated pure titanium C.X. Wang *, M. Wang School of Mechanical and Production Engineering, Nanyang Technological University, 50Nanyang Avenue, Singapore 639798, Singapore Received 3July 2001; accepted 24July 2001 Abstract Bone-like apatite formed on the surface of pure titanium pretreated with NaOH solution after having been immersed in simulated body fluid (SBF).In the present study, electrochemical impedance spectroscopy (EIS)measurement was used to investigate the nucleation and growth of apatite on chemically treated pure titanium immersed in the SBF solution. An appropriate equivalent circuit model was constructed to describe the nucleation and growth of apatite. It was found that EIS is a useful method for investigating the nucleation and growth of bone-like apatite on pure titanium pretreated with NaOH solution. It may quantify apatite growth on pretreated titanium substrates. D 2002Elsevier Science B.V . All rights reserved. Keywords:Electrochemical impedance spectroscopy; Alkaline treatment; Pure titanium; Bone-like apatite; Nucleation and growth 1. Introduction Calcium phosphate ceramics, such as hydroxy-apatite (HA)-coatedtitanium and its alloys, are among the most promising implant materials for orthopedic and dental applications. However, prob-lems such as low bond strength between the coating and the substrate and nonuniformity across the thick-ness of the coating are often encountered with these coatings [1]. Recently, it has been reported that chemically treated titanium can induce bone-like apatite forma-tion in vitro and in vivo [2–4],which means that titanium and its alloys have potential bioactivity. Treatment with a NaOH solution produces a sodium titanate gel layer on titanium surface. The gel layer has the ability to induce formation of bone-like apatite during immersing in simu