新型聚羧酸盐助洗效率的评价.pdf

第 35卷第 1期 应 　用 　化 　工 Vol. 35 No. 1 2006年 1月 App lied Chem ical Indu stry Jan. 2006 新型聚羧酸盐助洗效率的评价 姜文勇 ,王 　珩 ,崔德生 (哈尔滨理工大学 化学与环境工程学院 ,黑龙江 哈尔滨 　150080) ( ) 摘 　要 : 以聚羧酸盐 玉米淀粉氧化产物 作洗涤助剂 ,用表面张力法测定了新型聚羧酸盐与三聚磷酸钠聚丙烯酸 ( ) 钠对硬脂酸钠在硬水中的临界胶束浓度 CMC , 以此为依据评价其助洗效率 。结果表明 ,助洗效率按三聚磷酸钠 、 新型聚羧酸盐 、聚丙烯酸钠递减 。新型聚羧酸盐具有 良好的助洗效果 ,对环境无污染 ,可作为洗涤助剂的主选品 种 。 关键词 :新型聚羧酸盐 ;临界胶束浓度 ;助洗效率 中图分类号 : TQ 649. 5 　　　文献标识码 : A 　　　文章编号 : 167 1 - 3206 (2006) 0 1 - 0038 - 03 Eva lua tion of wa sh inga iding activ ity of novel sod ium polycarboxyla te J IAN G W en y ong, WAN G H eng, CU I D esheng (Chem istry and Environm ental Engineering College, H arb in U n iversity of Science and Technology, H arb in 150080, Ch ina) A b stract:One k ind of sodium po lycarboxylate con tain ing carboxyl ha s been gained by corn starch is oxi dated by oxygen directly, u sing it a s auxiliary detergen t. The influence s of novel sodium po lycarboxylate, sodium tripo lyp ho sp hate and sodium po lyacrylate a s detergen t auxiliary agen t on the critical m icelle con cen tration (CMC) of sodium stearate in hard water were studied by u se of su rface ten sion m ethod. The e valuation of their wa sh ing aid ing efficiency wa s also m ade. It showe s that the decrea se order of wa sh ing ai ding effectivene ss is sodium tripo lyp ho sp hate, novel sodium po lycarboxylate and sodium po lyacrylate. No vel sod ium po lycarboxylate by oxidized corn starch shou ld be taken a s m ain detergen t auxiliary agen t for its sup eriority of h igher wa sh i