yagce3+(ga,la,pr)荧光粉的制备及性能研究-preparation and properties of yag ce 3 + ( ga, la, pr ) phosphor.docxVIP

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yagce3+(ga,la,pr)荧光粉的制备及性能研究-preparation and properties of yag ce 3 + ( ga, la, pr ) phosphor.docx

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yagce3(ga,la,pr)荧光粉的制备及性能研究-preparationandpropertiesofyagce3(ga,la,pr)phosphor

PreparationandcharacterizationofYAG:Ce3+（Ga,La,Pr） phosphorAbstractIn the liquid crystal display (LCD) and large screen display, White LED has been widely used as the backlight. The performance requirements of LED become stringent./s?wd=especially Especially, the color rendering index and luminous efficiency of LED have higher requirements. In the backlight application, most of ordinary white LED is generated by the blue light and yellow light. The disadvantage is a high color temperature, the lack of a red component in spectrum. This white LED has small color gamut, lowcolor rendering index. To solve the problem，based on the YAG yellow phosphor,doping Ga, La, Pr made new kinds of phosphor. Study on four kinds of phosphor preparation of (Al1-x，Gax)5Y3O12:Ce3+、Al5( Y1-x, Gax)3O12:Ce3+、Al5(Y1-x，Lax)3O12: Ce3+、(Al1-x，Gax)5 (Y1-y，Pry)3O12: Ce3+ ,and its application in white light LED. Inorder to improve the luminescent properties of white LED，expanding the applicationarea. The main results are as follows:The new four phosphors are prepared using high temperature solid-state method， and test the emission spectra of the new phosphors：（1）(Al1-x，Gax)5Y3O12:Ce3+ and Al5( Y1-x, Gax)3O12:Ce3+ phosphor, when element Al is replaced by element Ga willcause blue shift of the emission peak, and the blue shift is about 8 nm. Red shift of emission peak can be observed when Y element is replaced by Ga element, and thered shift is about 11 nm. （2）(Al1-x，Gax)5 (Y1-y，Pry)3O12: Ce3+ phosphor, Twoemission peaks of 532 nm and 610 nm are detected when Ga and Pr are doped. （3） Al5(Y1-x，Lax)3O12: Ce3+ phosphor, when element Y is replaced by element La will cause red shift of the emission peak, the emission peak at 549m.Four kinds of phosphor were LED package aging test. The earlier stage, attenuation is more serious. In later stage of aging, the luminous intensity remained about the same. The color difference is in the allowed range. The phosphors can improve the color gamut of the backlight