废旧印刷电路板基材填充聚丙烯复合材料的性能分析-performance analysis of polypropylene composite filled with waste printed circuit board substrate.docxVIP

大。在同一剪切应力下，随着 WPCBB 含量的增加，复合材料的黏流活化能呈现先减小后增大的趋势，在 WPCBB 含量为 20%时，黏流活化能最小；相对于温度的变化，复合 材料的黏度对剪切应力的变化更为敏感。4. WPCBB 含量对复合材料结晶行为的影响：WPCBB 加入后，PP 由单一的 α 晶型转变为 α 和 β 两种晶型并存，黑十字消光现象 逐渐变得不明显，球晶结构遭到破坏，球晶数目增多尺寸减小最终消失。WPCBB 的加 入还提高了 PP 的结晶度和结晶速率，结晶起始温度有所提高，说明 WPCBB 起到了异 相成核的作用。利用 Avrami 方程和 Mo 法可以很好地描述复合材料的等温结晶和非等 温结晶动力学过程，并通过拟合得到了 PP 及 PP/WPCBB 复合材料的结晶动力学各项参 数。关键词：聚丙烯，废旧印刷电路板基材，力学性能，流变行为，结晶行为Study on the Properties of PP Matrix Composites Filled With The Wasted Printed Circuit Boards BasementABSTRACTAs the rapid development of science technology and society, the update rate of electronic products accelerated, leading to a huge amount of electronic waste. Printed circuit boards are essential compoments to all kinds of electronic products and causing a severe environmental contanmination. Most of the attention of current study was paid on the recycle of metal elements contained in the wasted printed circuit boards, while, as for the wasted printed circuit boards basement (WPCBB) of high value, the cineration and filling treatments were the common method, which resulted in a serious waste of resource and gread danger to the environment.In this paper, firstly, the ingrediants and morphology of wasted printed circuit boards basement (WPCBB) were studied. Then the PP/WPCBB composites were prepared by melting blending, with WPCBB after surface treated as reinforcing material and PP as the matrix resin, implementing the high-value reuse of wasted resource as well as reducing the environmental pollution.The main studying contents are as follows:Characterization of WPCBB’s ingrediants and morphologyWPCBB’s ingrediants and morphology were charactered via infrared spectroscopy (FT-IR), thermogravimetric analysis (TG), muffle sintering and scanning electron microscope (SEM). Results showed that WPCBB is consisted of glass fiber, epoxy resin, phenolic resinand so forth; it coule be acquired that the length of glass fiber was between 180～360μm andthe diameter of glass fiber was about 7μm, wi