高含氮难降解土霉素生产废水治理的分析-analysis on treatment of oxytetracycline production wastewater with high nitrogen content and difficult degradation.docxVIP

摘要本研究通过试验室试验，对土霉素废水的厌氧和好氧生化处理特性进行f 系 统的研究，研究表明: (1) 控制废水中土霉素效价 200μg/mL 时，通过一定时间 对厌氧污泥的驯化培养，废水有机污染物的厌氧生化处理效果派基本可稳定在一 个较好的水平 o (2)在实际的土霉素生产废水 COO/TN 为 7.2 的碳氮比值条件下，废水有机污染物的厌氧生化过程被明显抑制:而废水TN 中 NH3-N 比例过高，对;育机污染物的厌氧硝化过程更为不利。 C )采用厌氧一好氧与循环回流硝化、反 硝化流程，处理高含氮、高残留毒性难降解的土霉素废水具有较好的处理效果。 在进水浓度 2000-3000 mg/L 的条件下，系统对有机物的去除率稳定在 80%左右。 (4)采用硝化一反硝化处理系统，当回流比为 1:2-1:3.5 时，硝化一反硝化 系统可去除 55%--60%。关键词:土霉素生产废水:土霉素效价:厌氧:好氧:硝化:反硝化ABSTRACTηlis paper deals with biochemical characteristics of terramycin wastewater degraded by anaerobic and aerobic microbes .Through the experimentation carried out on a labscale，a systematical study shous that (1)When terramycin was kept at tbe levels of 200μg/mLini臼waste wate飞a defmite time of cul阳ring anaerobic organic contaminations was able to produce a steadiness of effects on its biochemical treatment.(2)When the rate of carbon to nitrogen (COD厅N)inw侃侃 water from terramycin production was practically 7.2，the biochemically anaerobic process oforgenism in waste water was obviously inhibited a higher ratio of NH3-N in TN ofw侃侃 water was not good for anaerobic nitrification process oforganic contaminations .(3) An anaerobic-aerobic process and a cyclereωm of nitrification-denitrification had a better impact on te町缸nycm waste water with high nitrogen content and potently poisonous residues not e部Y to be degraded by micro-organism. When the inffuent wagIL，the organism removal rate by using the nitrificationequipmentwasωnstangtly at 80% or so.(4)When ni创fication-denitrification sys阳10阴归时 and the retwn flow ratio was 1:2--]:3.5，55O/0--6Q01o of nitrogen ω1beremoved.Keywords:Terramycinwastewater ，Terramycin古Anaerobic，AerobiC，Nitri ficationDen itrification离合氮难辩解土霉素生产废水治理的研究1 引言1.1抗生素的生产摄述1.1.1 抗生素的定义抗生，絮是青霉素、链霉素、四环索、红霉素等一类化学物质的总称，是微生 物、植物、动物在其生命过程中产生的?能在低微浓度下选择性的抑制或影响位 种微生物或肿瘤细胞的有机物质，有些可以用化学法或生物化学法对其进行结构 改造。抗生素的发现和应用使严整危害人类健康和生命的许多疾病得到有效的控 制q 抗生素还被广泛的应用于农业和畜牧业，在 E延民经济各个方商发挥其重要作 用。由于卒期发现的一些抗生素如青霉素、链霉素等均来源于微生物部生命活动， 因此，过去把抗生素的来源局限于微生物，事实上不仅某