pa6uhle共混材料的力学破坏行为研究-study on mechanical failure behavior of pa 6u hle blends.docxVIP

AbstractThe blend named as UHLE consist of high density polyethylene、linear low density polyethylene、ultra high molecular weight polyethylene and ethylene-acrylicacid copolymer was prepared by melt blending with the same constitutional ratio. And then polyamide 6 (PA6)/UHLE blends were prepared with several constitutional ratios. The tensile behaviors and fracture toughness of PA6/UHLE blends were tested in this study. The melt behaviors of tensile specimens were carried out by DSC. The morphology and fracture topology of PA6 and its blends were observed by scanning electron microscopy (SEM). Finally, an energy dissipated model was put forward to interpret the energy dissipating during fracture.The tensile testing suggests that the tensile behaviors of PA6/UHLE blends with different UHLE contents are different. As to the same blends, the tensile behaviors of origin and post-treated specimens are different. Specially, tensile double yielding phenomenon exists in almost in all neat PA6 specimens and partial PA6/UHLE blends. Double yielding phenomenon was depressed and cold draw ratio decrease with increasing the UHLE content.The Charpy impact testing exhibits that PA6 and PA6/UHLE blends notch specimens are under brittle fracture and the impact strength decreases with increasing the UHLE content. In contrast, the quasi-static single edge notch three points bend (SENB) testing show that there is a brittle-ductile fracture transition when the ratio of notch length to specimen wide reaches to 0.8, while as to PA6/UHLE blends, all notch specimens show ductile fracture without depending on the notch length and there are stress whitened zones around the crack of the fractured specimens. The fracture toughness calculated from the SENB testing by locus method displays that, increasing UHLE content, the critical initial crack energy decrease while the crack resistance at the maximum load and the steady crack resistance increases on the beginning and then decreases with. From t