pllaposs有机无机杂化材料的结晶行为研究-crystallization behavior of pll aposs organic-inorganic hybrid materials.docxVIP

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pllaposs有机无机杂化材料的结晶行为研究-crystallization behavior of pll aposs organic-inorganic hybrid materials.docx

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pllaposs有机无机杂化材料的结晶行为研究-crystallization behavior of pll aposs organic-inorganic hybrid materials

暨南大学暨南大学硕士学位论文 II II Abstract In recent years, polyhedral oligomeric silsesquioxane (POSS) has attracted a lot of attentions among the inorganic nanocomposite materials, due to mechanical property, electrical properties, thermal properties, optical properties, flame resistance, biocompatibility and so on. The high-performance POSS can improve the performance of PLA and broaden its application fields. For low mechanical strength, bad thermal property, slow degradation rate of PLA, we introduce POSS nanocage into PLLA and systematically investigate the crystallization behavior of the hybrid material. In this study, water-soluble POSS was synthesized via hydrolysis condensation. POSS-AH was used to initiate ring-opening polymerization of lactide under microwave conditions, grafting polylactic acid segment on POSS. And the segment length can be controlled by feed ratio of POSS-AH and lactide. Banded spherulites can be obtained from blends of hybrid materials and pure PLLA under proper conditions. Crystallizaed temperature and thickness of wafer are two critical factors for the formation of banded spherulites. The interface colour of banded spherulites changes with thickness of wafer, covering all visible light wavelengths. Cracks can be observed in spherulites while cooling. For there is some relationship between cracks and mechanical property, we study the influence of POSS on the cracks in spherulites, along with other key factors. Keywords：PLA;POSS;organic-inorganic hybrid material;banded spherulite; concentric ring cracks III III 目录摘要 I HYPERLINK \l _bookmark0 Abstract II HYPERLINK \l _bookmark1 目录 III HYPERLINK \l _bookmark2 第一章绪论 1 HYPERLINK \l _bookmark3 1.1 聚乳酸 1 HYPERLINK \l _bookmark4 PLA 的优点及缺点 1 HYPERLINK \l _bookmark5 PLA 的优点 1 HYPERLINK \l _bookmark6 PLA 的缺点 2 HYPERLINK \l _bookmark7 1.1.2 PLA 的合成 3 HYPERLINK \l _bookmark8 1.1.2.1 直接缩聚法 3 HYPERLINK \l _bookmark9 1.1.2.2 溶液缩聚法 3 HYPERLINK \l _bookmark10 1.1.2.3 熔融缩聚法 3 HYPERLINK \l _b