新型碳纳米复合材料的制备及其葡萄糖传感器的分析-preparation of new carbon nanocomposites and analysis of their glucose sensors.docxVIP
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新型碳纳米复合材料的制备及其葡萄糖传感器的分析-preparation of new carbon nanocomposites and analysis of their glucose sensors
本文通过简便的快速还原法法合成了钯、铂合金负载的碳纳米纤维纳米复合物。由于碳纤维存在,使得钯、铂合金均匀的分散在其表面上,再以戊二醛交联固定葡萄糖氧化酶,得到葡萄糖传感器。根据酶与底物特异性反应对葡萄糖进行高灵敏性检测,检测范围较宽2.5μM~11.1mM,灵敏度达到159.5μAmM-1cm-2,为酶催化氧化葡萄糖的检测提供一个有效、简便、灵敏的途径。关键词:氧化铜介孔碳纳米复合物;二氧化铈-介孔碳纳米复合物;钯、铂合金碳纳米纤维复合物;电流型葡萄糖传感器;无酶葡萄糖传感器IABSTRACTWiththerapiddevelopmentofnanotechnology,nanometercompositematerialisbytwoormoredifferentkindsofmaterial,throughphyscialorchemicalmethod,inthemacoscopicandmicroscopiconwithanewperformanceofthematerial.Allkindsofmaterialinperformancefromeachother,producesynergisticeffect,makethecomprehensiveperformanceofcompositematerialissuperiortotheoriginalcomponentmaterialsandmeetvariousrequirements.Newtypecarbonnanocompositesincreasinglysubjecttoawiderangeofvariousfiledresearchersattentionforitssuperiorperformance.Thispaperfocusesontheanalysisofthechemicalcombinationofthemostactiveareasofnanocompositetechnologyandelectrical-preparationofnewcarbonnano-compositemodifiedelectrode.Glucoseelectrochemicalsensorisoneofimportantresearchdirectionoftheelectroanalyticalchemistry,tobedividedaccordingtothepresenceorabsenceoftheenzyme,dividedintonon-enzymesandenzymeglucosesensortwocategories.Detectionofglucoseinthefoodindustry,pharmaceuticalandclinicalindustrieshasfar-reachingsignificance.Insituattachmentofcupricoxidenanoparticles(CuONPs)tomesoporouscarbons(MCs)forsensitiveamperometricnon-enzymaticsensingofglucoseMCswerepreparedthroughasimpledouble-templatemethodinthisarticle.Withnitrogen-nitrogendimethylacetamideassolvent,mixingMCsandcoppernitrate,throughagreenchemicalprecipitation,insituweresynthesizedstabilizationpropertiesofCuONPs-MCsnanocomposites.DuetothelargerspecificsurfaceareaoftheMCsaswellastheuniformityoftheholemakestheCuONPswereuniformlydispersedonthesurface,greatlyincreasingthesensitivityofthecatalyticoxidationofglucose,upto1154.1μAmM-1cm-2,thedetectionlimitaslowas0.1μM,toprovideaneconomic,simpleandgreenchannelforenzyme-freedetectionofglucose.Thepreparationofceriumoxid-mesoporouscarbon(CeO2NPsII-MCs)nanocompositeandappliedinglucosesenso
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