烷基芳烃液相氧化历程的研究.pdf

博后出站报告：烷基芳烃注相氧化过程的研究 Abstract Oxidationof aromatic chemical myl hydrocarbonis趾important process．A WaS research carriedoutinthis to comprehensiveprogram understandthe paper mechanismandl【incticsof aromatic oxidation MC aIlbl hydrocarboncataIyzedby in acctioacidand Co／Mn／Br (Mid-Century)process,whichproceeds catalyzedby ternary workandresultsareoutlinedasfollows． system．The ． mechanismofMC wasstudied．A radical Firstly,The process comprehensive chainmechanism foroxidation aromatics was ofmethyl hydrocarbon proposed,from whichthekineticmodelwith form and forthemainsidereactionsWele hyperbolic derived．Alot werecarried outto model．Both ofexperhnents vcri匆the experimental industrial and results theevidences to the for provide supportmodel．Experiments kinetic oxidationwerecarried study m-xylene out，influencesof oftoluene，p-xylene concentration,Co／Mnvarious conditions temperature，catalyst ratio，underprocess were databaseandmodelswereobtained． investigated,the effectso