吩噻嗪取代β-二酮稀土配合物的合成及荧性能研究毕业论文.docx

本科学生毕业论文论文题目：吩噻嗪取代β-二酮稀土配合物的合成及荧光性能研究学 院：化学化工与材料学院年 级：2009级专 业：应用化学姓 名：学 号导教师：2013年5月摘要有机配合物是一类介于有机物与无机物之间的化合物，是分子功能材料的主体，它既具有有机化合物的高荧光量子效率的优点，又有无机物分子的稳定性高、磁学性能良好的特点，因此被认为是一类最有应用前景的发光材料和磁性材料。稀土配合物具有光致发光效率高、光单色性好、稳定性高等诸多优点，使其作为电致发光利料显示了诱人的前景。β-二酮及其衍生物的配合物作为新型多功能材料在金属有机液晶、萃取试剂、化学位移试剂、防伪材料等方面已引起人们普遍的重视，近年又发现该类化合物同时具有光致发光及电致发光的双重性，还可以与基因发生一定的相互作用，对新型多功能材料的开发具有良好的应用前景。稀土β-二酮化合物是1,3-二羰基化合物与稀土离子的螯合物。由于这类配合物在照明、显示、显像、医学放射学图像、光纤通讯等领域潜在应用[1]，目前已成为最受欢迎和研究最为广泛的稀土配位化合物。因此，对新颖结构β-二酮稀土配合物的合成、结构及光致、电致发光研究显得具有尤为重要。研究表明，β-二酮类配体，如1,3-二苯基丙二酮（HDBM）、三氟乙酰噻吩甲酰甲烷（HTTA）的三重态能级与Eu3+的5D0能级匹配，1-苯基-3-甲基-4-乙酰基-5-吡唑啉酮（HPMP）的三重态能级与Tb3+的5D4能级很匹配，无论是在固态还是在溶液中，都具有很高的光致发光效率，这是目前研究最为广泛的二酮配体(如图所示)。图1. 常用二酮配体关键词稀土配合物；发光；吩噻嗪；β-二酮；荧光性AbstractOrganic complex compound between organic and inorganic compounds, is the main molecular functional materials, has the advantages of high fluorescence quantum efficiency it has both organic compounds, and the characteristics of stability of inorganic molecular high, good magnetic properties, so it is considered to be luminescent materials and magnetic materials for a class of the most the application prospect of the. Rare earth complexes have high photoluminescence efficiency, light color is good, high stability, and many other advantages, make it as electroluminescent material shows attractive prospect. Complexes of β - two ketone and its derivatives as a new type of multifunctional material has attracted widespread attention in the aspects of organometallic liquid crystal, extraction reagent, chemical reagent, anti-counterfeiting materials, in recent years, found that the compounds with photoluminescence and electroluminescence duality, also can interact with certain gene, has good prospects for the development of new functional materialsRare earth - two ketone compounds are chelate 1,3- two carbonyl compound and rare earth ions. Because this kind of complexes in the potential application of [1] lighting, display, imaging, medical radiology imag