致密性聚氨酯微胶囊相材料的制备毕业设计.docxVIP

毕业设计（论文）题 目： 致密性聚氨酯微胶囊相变材 料的制备 学 院： 纺织与材料学院 专业班级： 轻化工程11级（3）班 指导教师： 职称： 讲师 学生姓名： 学 号： 摘要 相变储能技术能够显著提高能源利用率,有效缓解能源紧缺问题。而相变储能技术大规模应用的困难在于相变材料容易泄漏,需要对其进行封装。目前,得到国内外广泛关注、具有较高实用价值的封装技术是微胶囊化技术。本文立足于此，以硬脂酸丁酯为芯材, 苯乙烯马来酸酐共聚物(SMA)为乳化分散剂, 采用界面聚合制备微胶囊相变材料, 其壁材分为两种：一种是甲苯-2, 4-二异氰酸酯(TDI)和聚醚多元醇反应形成的, 一种是脂肪族异氰酸酯（IPDI）与聚醚多元醇反应形成的聚氨酯壳层。研究了合成过程中乳化转速、乳化时间、反应温度、反应时间、芯材与壁材用量等因素对微胶囊表面形貌及各项性能的影响。采用差示扫描量热仪(DSC)、热重分析仪(TGA)、扫描电镜(SEM)、光学显微镜等分别对微胶囊的热性能、表面形态做了研究和分析。结果表明, 所制备微胶囊的致密性和耐热稳定性均比单层微胶囊有很大程度的提高。 关键词：微胶囊 ，聚氨酯 ，相变材料，界面聚合，硬脂酸丁酯Abstract The energy storage technology can improve the energy utilization rate, effectively alleviate the shortage of energy. The difficulty of large scale application of phase change energy storage technology is that phase change materials are easy to leak and need to be encapsulated.. At present, the encapsulation technology which is widely concerned at home and abroad, and has the high practical value is the micro encapsulation technology. Based on the, with n-Butyl stearate as core material, styrene maleic anhydride copolymer (SMA) for emulsion dispersant, by interfacial polymerization preparation of microencapsulated phase change material, the wall material is divided into two: one is toluene 2, diphenylmethane diisocyanate (TDI) and polyether polyol be formed. Another is the formation of aliphatic diisocyanate (IPDI) and polyether polyol reaction of polyurethane shell.The effects of emulsifying speed, emulsifying time, reaction temperature, reaction temperature, reaction time, the amount of core material and wall material on the surface morphology and properties of microcapsules were studied.The thermal properties and surface morphology of microcapsules were studied by differential scanning calorimetry (DSC), thermogravimetric analyzer (TGA), scanning electron microscopy (SEM) and optical microscope.. The results showed that the compactness and heat resistance of the microcapsules were improved compared with the single microcapsule.Key word: microca