高分子材料和应用 Chapter 2 Commodity Plastics.pptVIP

Ethylene copolymer series Acrylic ester decreases the crystallinity of the polymer Key benefits of ethylene acrylic ester copolymers Excellent thermal stability Excellent adherence to many substrates (polyethylene, polystyrene, polypropylene, OPP, etc.) Good chemical resistance Good elastic properties Excellent mechanical behavior at low temperature Ethylene - Acrylic Ester copolymers Ethylene copolymer series They can be divided into several product families depending on the acrylic ester type (methyl, ethyl or butyl acrylate) Third monomer - MAH : maleic anhydride - GMA : glycidyl methacrylate. - Increase final adhesion properties - Heat resistance or long term ageing properties. The roles of third monomer Ethylene acrylic ester terpolymers Ionomers : An ionomer is an ion containing polymer. It is more than just a polymer with ionic groups. We call any old polymer with ionic groups a polyelectrolyte special kind of polyelectrolyte. containing both nonionic repeat units and small amounts of ion containing repeat units less than 15% of polymer Characteristics : The polar groups tend to cluster together, away from the nonpolar polymer backbone chains not closslinked polymer a type of thermoplastic called a reversible crosslinker This phenomenon allows for a polymer with the properties of an elastomer and the processability of a thermoplastic. These ionomers are sometimes known as thermoplastic elastomers When heated, ionic groups lose their attractions and the chains more around freely. Reversible crosslinking behavior of ionomers Ionomers Example: Polymerization between ethylene and methacrylic acid ionomer Acidic property ethylene methacrylic acid Poly(ethylene-co-methacrylic acid) Semipermeable membrane Ion filter Fuel cells Electrodialysis Applications Dupon : Surlyn TM Dupon : Nafion TM Functional moiety Ethylene propylene rubber EP rubber (EPR), poly(ethy