第十章 配位化合物（Tenth chapter coordination compound）.docVIP

第十章 配位化合物（Tenth chapter coordination compound） Tenth chapter coordination compound 1. anhydrous CrCl3 and ammonia can form two complexes, which are equivalent to CrCl3, 6NH3 and CrCl3, 5NH3. Adding AgNO3 solution from the first kind of complexes in aqueous solution of almost all of the chlorine precipitation is AgCl, and from second with the precipitation of equivalent composition of chlorine content in 2/3 AgCl can only matter in aqueous solution, adding NaOH and heating two kinds of solution are no NH3 taste. The internal and external conditions are calculated from the form of complexes, and the charge number, the oxidation number of central ions and the name of complexes are pointed out. Answer: the first kind: [Cr (NH3) 6]Cl3 ion charge number 3+: That is, [Cr (NH3) 6]3+, Cr (III), three chloride, six chromium (III). Second species: [CrCl (NH3), 5]2+, Cr (III), two chlorine chloride, and five ammonia chromium (III). 2. name the following complexes and point out the central ions and oxidation numbers, ligands and coordination numbers. (1) [Co (NH3) 6]Cl2 (2) K2[PtCl6] (3) Na2[SiF6] (4) [CoCl (NH3), 5]Cl2 (5), [Co (EN), 3]Cl3 (6), [CoCl (NO2) (NH3), 4]+ Answer: Naming Central ion oxidation number Ligand coordination number (1) two chloride, six ammonia cobalt (II); +2 NH3 Six (2) hexachloro platinum (IV) acid potassium +4 Cl- Six (3) six fluorine silicon (IV) sodium salt; +4 F- Six (4) two chlorine chloride, five cobalt cobalt (III); +3 Cl-, NH3 Six (5) three chloride three (ethylenediamine) cobalt (III) +3 En Six (6) one chlorine, one nitro, four cobalt cobalt (III) coordination ion; +3 Cl-, NO2-, NH3 Six 3. write the chemical formula of the following complexes (1) two sodium thiosulfate (2), three nitro three cobalt cobalt (III) (3) two three ammonia chloride chloride hydrated cobalt (III) (4) two chloro two hydroxy diamino platinum (IV) (5) sulfuric acid, chlorine, ammonia, two (ethylenediamine), chromium (III); (6) two chlorine ions a grass (ethylenediamine) F