Kinetics of the Decomposition ofCrystal Violet对结晶紫的分解动力学.docVIP

Kinetics of the Decomposition of Crystal Violet NAME:________________________________________ PERIOD:_________ Prelab Follow the data analysis procedure described in the lab. 1. Decide graphically whether the data for the decomposition of NO2, follows zero, first, or second order kinetics. NO2 (g) ( NO(g) + 1/2 O2 (g) Label the columns with the data calculated and enter the data. Sketch the graphs generated with labeled axes. Use the back of this page. State the order of the reaction Determine the value of the rate constant. [NO2] Time (min) 0.020 0 0.015 0.50 0.012 1.0 0.010 1.5 0.0087 2.0 2. Decide graphically whether the data for the radioactive decay of an isotope follows zero, first, or second order kinetics. Label the columns with the data calculated and enter the data. Sketch the graphs generated with labeled axes. Use the back of this page. State the order of the reaction Determine the value of the rate constant. Mass (mg) Time (day) 500 0 389 1 303 2 236 3 184 4 143 5 112 6 Kinetics of the Decomposition of Crystal Violet Theory: Crystal Violet reacts with hydroxide ion to form a colorless product. The equation for the reaction is shown here: The kinetics of the reaction is followed spectrophotometrically as the color of the Crystal Violet decreases with time using a computer interfaced to a Vernier colorimeter. According to Beer’s Law: A = ( b c Absorbance = (molar absorptivity) (cell path length) (molar concentration) The absorbance of the Crystal Violet solution is proportional to its molar concentration since the molar absorptivity at a particular wavelength and the cell path length are constants. The decrease in concentration of the Crystal Violet is determined by monitoring the decrease in absorbance of the solution with time. The rate law for the reaction is given by: Rate= k [Crystal Violet]a [OH-1]b In this experiment, the concentration of the OH-1 ion will be large compared