Modelingoforganicpollutantdestrucioninastirred2tankreactorbyozonation专业英语论文.docx

Modeling of organic pollutant destruction in a stirred2tank reactor by ozonationCHENGJiang1 , YANG Zhuo2ru1 , CHEN Huan2qin1 , KUO C. H. 2 , ZAPPI E.M. 2Abstract :Destruction of organic contaminants in water by ozonation is a gas2liquid process which involves ozone mass transfer and fast irreversible chemical reactions. Ozonation reactor design and process optimizing require the modeling of the gas2liquid interactions within the reactor. In this paper a theoretical model combining the fluid dynamic and reaction kinetic parameters is proposed for predicting the destruction rates of organic pollutants in a semi2batch stirred-tank reactor by ozonation. A simple expression for the enhancement factor as our previous work has been applied to evaluate the chemical mass transfer coefficient in ozone absorption. 2 ,42dichlorophenol (2 ,42DCP) and 2 ,62DCP or their mixture are chosen as the model compounds for simulating , and the predicted DCP concentrations are compared with some measured data.Keywords :dichlorophenol destruction ; ozonation ; stirred2tank reactor ; enhancement factorIntroduction Because of the high oxidation potential of ozone (O3 ) , ozonation has been regarded as a promising method for drinking and waste water treatment. A wide range of organic pollutants in water can be degraded by O3 , O3 combined with H2O2 or UVlight , which are known as Advanced Chemical Oxidation Processes (AOPs) . Compared to the traditional treatment technologies , such as activated carbon adsorption or biodegradation , chemical oxidation with ozone offers the advantages ofgreater rate and extent of contaminant destruction. Although there are numerous reports (Hoigne , 1983 ; David , 1991) on the ozonation kinetics research regarding reaction rate constant , stoichiometric ratio and the identification of intermediates , application of these reaction kinetics to yield essential information for successful reactor and process design has not been received sufficient attention ( Yu