溶胶凝胶自燃烧方法在多孔氧化铝模板上合成羟基磷灰石纳米管阵列-材料合成化学课件PPT.pptVIP

Synthesis of Hydroxyapatite Nanotubes Array in Porous Alumina Template by Sol-gel Auto-combustion 溶胶凝胶自燃烧方法在多孔氧化铝模板上合成羟基磷灰石纳米管阵列 Catalogue 1.Fundamental knowledge 2.Synthesis method 3.Microstructure and properties 4.Mechanism 5.Conclusion Fundamental Concepts Why study hydroxyapatite nanotubes array？ hydroxyapatite （HAP） 中文名：羟基磷灰石，化学式：Ca10 ( PO4 ) 6 (OH) 2 HAP: the compositional and biological similarity to natural tissues, hard tissue replacement, drug/gene delivery carrier and biocompatible coating NHAP turn out to possess cytotoxicity(细胞毒性） and apoptosis-induction（诱导细胞死亡） in some cancerous cells. Lackage of synthesis methods for NHAP array Fundamental Concepts What is sol-gel auto-combustion method? It is a unique combination of the combustion and the chemical sol–gel process. When heating the organic gel or the organic salt the metal nitrate, the reactants combust and produce lots of gas. Reaction can maintain itself and we can synthesize the product we needed The advantage of this method： Compared with the conventional sol–gel process, this method exploits the advantages of simple preparation and a resulting ultrafine and homogeneous powder at low temperatures in a single step. Flow Chart of Synthesis of NHAP Array Ca(NO3)2.4H2O+ethylene glycol 1 : 1.5 PO(CH3O)3+dehydrous ethanol + homogenous clear sol gel dried gel Annealed at 600 ℃ in a rate of 2℃ for 2h The resulting template composites The final products Mixed at 80℃ and adjusted the PH AAO template was immersed into the sol for 10mins at RT and taken out from sol dried under vacuum at 130 ℃ for 2h Removed the deposits on both faces of the template by polishing dissolved in 6M NaOH solution to remove the Al2O3 to obtain self-sustained nanotubes rinsed with de-ionized water several times Properties of Dried Sol 1.DTA/TG The phenomena: a sharp and intense exothermic peak emerged at about 220 ?C, and the corresponding weight loss was approximately 41% The reason: the exit