uhmwpecsw复合材料摩擦学性能研究-tribological properties of uhmwpecsw composites.docx

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2018-06-28 发布于上海
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uhmwpecsw复合材料摩擦学性能研究-tribological properties of uhmwpecsw composites.docx

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uhmwpecsw复合材料摩擦学性能研究-tribological properties of uhmwpecsw composites

摘要适的填料协同填充改性是一种改善UHMWPE复合材料摩擦学性能较好的方法，值得进一步研究。关键词：超高分子量聚乙烯，填充改性，硫酸钙晶须，纳米Al2O3，协同作用，摩擦磨损论文类型：应用基础研究II摘要Subject:StudyonTribologicalPropertiesofUHMWPECompositesFilledwithCSWSpecialty:PolymerChemisteyandPhysicsName:GanLihuiSupervisor:NiuYongpingABSTRACTUHMWPEisawidelyusedengineeringplasticforit’sversatileandexcellentproperties,suchasgoodself-lubrication,erosionresistance,wearingresistanceetc.However,its’applicationinwearandfrictioncircumstancewererestrictedbysomeshortcomingssuchaslowerfacialhardnessandpoorabrasivewear-resistance.Inthisthesis,CSWandnano-Al2O3filledUHMWPEcompositeswerepreparedandthemodificationeffectofthesefillerstothehardnessandtribologicalpropertiesoftheobtainedcompositeswerestudied.Filledcompositeswerepreparedfollowingthetraditionalphysicalmixingandhot-pressingprocedures.Thefrictionandwearbehavioroftheobtainedcompositesdiskswereinvestigatedonahigh-temperatureatmosphereQG-700modeltesteragainstAISI1045steelballunderdryslidingcondition.ThewornMicro-morphologyofthecomposites’surfaceswasrecordedbySEM.TheelementchemistryofthewornsurfacewasanalyzedbyEDSalpharayspectrometer.Thewearscarwidthswereobservedby3Dmorphologymeter.ThefacialhardnessofthematerialswasmeasuredbyShoredurometer.TheresultsshowthattheadditionoftheCSWfillercaneffectivelyincreasethehardnessandtribologicalpropertiesandlowerthefrictioncoefficientoftheUHMWPE/CSWcomposites.ThewearingresistanceandthefrictioncoefficientoftheUHMWPE/CSWcompositesincreasewiththeloadandtheslidingspeedincreasing.WiththefillingrateoftheCSWfillersincreasing,theabrasionmechanismoftheUHMWPE/CSWcompositeschangedfromadhesivewearandthermoplasticdeformationtoslightabrasivewear.TheoptimalfillingrateofCSWfillerincompositesisabout20%.TheCSWfillersplayacertainroleintheheterogeneousnucleation.ComparingwiththeCSW,nano-Al2O3fillershavethesimilarpositiveeffectinIII摘要improvingthehardnessandtribologicalpropertiesoftheUHMWPE/nano-Al2O3composites.Nano-Al2O3canlowerthefrictioncoefficientoftheobtainedcomposites.Theoptimalfillingrateofnano-Al2O3