若干多功能环境响应型微纳米材料的合成、改性与应用探索-化学工程专业论文.docx

nanomaterials are simultaneously endowed with well-retained properties of interest, excellent stability and smart properties: they exhibit superior stability under various conditions and the solution colors, absorption properties, fluorescent properties, aggregation behaviors, and catalytic activities can be smartly regulated by temperature, NIR light, and pH.In order to enhance the design space of nanomaterials, we have successfully extended the application of EHD co-jetting technique from producing multicompartmental soft materials to generating bicompartmental inorganic particles. After solving the problem that the conventional “reactive” jetting process cannot be used to prepare inorganic particles, we have developed the “non-reactive” EHD co-jetting process and produced three kinds of polymer-inorganic composited particles. After calcination, the sacrificing polymer template can be removed and the inorganic precursors are condensed into inorganic oxides. Either before and after calcination, the particles have well-defined spherical shapes and the bicompartmental properties can be proved by the clear interface between the two distinct compartments. CNT can be selectively grown from one hemisphere of the TiO2 Janus catalysts, indicating that the multicompartmental inorganic particles can be used as anisotropic catalysts for spatially controlled catalytic reaction.KEY WORDS ： Nanomaterials ； Functionalization ； Stimuli-Sensitivity ；Anisotropic; Electrohydrodynamic co-jetting目录第一章 文献综述11.1 典型无机纳米材料及其多功能化11.1.1 碳纳米材料 21.1.2 金纳米材料 91.2 环境响应型纳米材料111.2.1 环境响应型聚合物 121.2.2 环境响应型纳米凝胶 151.2.3 可逆加成-断裂链转移（RAFT）自由基聚合 17各向异性（Anisotropic）微纳米材料 191.3.1 补缀型（Patchy）微纳米颗粒 20多室型（Multicompartmental）微纳米颗粒 22静电共雾化技术（Electrohydrodynamic co-jetting） 231.4 论文的研究思路和意义26第二章 葡聚糖基双重环境响应型聚合物的合成及其自组装行为292.1 引言292.1.1 环境响应型纳米凝胶的多级自组装 292.1.2 研究目的与思路 302.2 实验部分312.2.1 PNIPAAm接枝葡聚糖（DexPNI）的RAFT聚合 312.2.2 双重环境响应型聚合物（SS-DexPNI）的合成与交联/解交联[94] 312.3 结果与讨论322.3.1 四种具有不同PNIPAAm接枝链长度的DexPNI的