不同形貌al2o3负载的钴 钌催化剂费 托合成催化性能的研究-study on catalytic performance of cobalt ruthenium catalyst supported on al2o3 with different morphologies for fischer - tropsch synthesis.docxVIP

Ru/Al2O3-c-1 和 Ru/Al2O3-f-1 相比，Ru/Al2O3-r-1 表现出最高的催化活性；在氢 气气氛下焙烧时，氧化铝纳米棒所负载的催化剂同样呈现最好的催化性能。 关键词：费-托合成；形貌；氧化铝；钴基催化剂；钌基催化剂  Abstract Fischer-Tropsch synthesis (FTS) is a very important chemical process for producing clean transportation fuels and valuable chemicals by the conversion of natural gas, coal and biomas. Cobalt-based catalysts are one of the most important candidates as the active component for FTS catalysts because of the higher selectivity for long chain hydrocarbons, the longer catalyts life and the lower activity for water-gas reaction (WGS). Although iron and cobalt are the common metals applied for FTS, Ru catalysts have been widely used for mechanism studies as possessing higher intrinsic activity and selectivity for long chain hydrocarbons. Thus, Ru catalysts are usually used as the model catalysts for the development of promising novel FTS catalysts. In this work, the different morphology of alumina support have been successfully synthesized by hydrothermal synthesis method. Co/Al2O3 and Ru/Al2O3 catalysts were prepared by incipient wetness impregnation technique. Catalysts with commercial alumina as support were also prepared for comparison. TEM, Nitrogen adsorption-desorption, XRD, TPR, TPD and oxgen titration were used to characterize these catalysts. The main results are as follows: （1）The specific surface area and porous structure of alumina support depends on its morphology, this is because the morphology of alumina support has a significant effect on the stacking and aggregation of alumina particles. The specific surface area decreased as follows : alumina nanofiber、nanosheet and nanorods. When the support has a higher specific surface area, the pore volume and pore size are smaller. （2）The morphology of Al2O3 support was also found to have a significant effect on Co3O4 crystallite size, catalyst reducibility and Fischer–Tropsch synthesis activity. Alumina nanofiber with the highest specific surface area leads to the catal